Solid state chemistry /
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Tunbridge Wells :
New Academic Science,
©2012.
|
Edición: | 2nd ed. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover
- Preface to the Second Edition
- Preface to the First Edition
- Contents
- Chapter-1. The Crystal Structure
- 1.1 Introduction
- 1.2 Crystal Planes and Miller Indices
- 1.3 Diffraction of X-Rays
- 1.3.1 Bragg�s Law of Diffraction
- 1.4 Reciprocal Lattice
- 1.5 Powder Method
- 1.5.1 Debye-Scherrer Method
- 1.5.2 The Powder Diffractometer
- 1.5.3 Indexing the Powder Patterns
- 1.5.4 Use of X-ray Powder Patterns
- 1.6 Crystal Defects
- 1.6.1 Point Defects
- 1.6.2 Defect Equations
- 1.6.3 Vacancy Concentration in a Metal
- 1.6.4 Schottky Defect Concentration in an Ionic Crystal1.6.5 Frenkel Defect Concentration
- 1.6.6 Dislocations
- 1.6.7 Plane Defects or Grain Boundaries
- Suggested Reading
- Chapter-2. Bonding in Solids
- 2.1 Introduction
- 2.2 van der Waals Forces
- 2.3 Covalency
- 2.4 Ionic Bond
- 2.4.1 Effect of Polarization
- 2.4.2 Empirical Lattice Energy Equation
- 2.5 Ionic Radii
- 2.6 Bonding in Metals
- 2.6.1 Pauling�s Valence Bond Method
- 2.7 Types of Solids
- 2.8 Mechanical Properties of Solids
- Suggested Reading
- Chapter-3. Structure of Solids3.1 Close Packing of Atoms
- 3.2 Structure of Metals
- 3.2.1 Body Centred Cubic Metals
- 3.3 Structure of Binary and Ternary Compounds
- 3.3.1 Octahedral and Tetrahedral Voids
- 3.3.2 Radius Ratio Rule
- 3.4 Structure of Ionic Crystals
- 3.4.1 Crystals with Stoichiometry MX
- 3.4.2 Crystals with Stoichiometry MX2
- 3.4.3 The Spinel Structure
- 3.4.4 The Perovskite Structure
- 3.4.5 Specific Defect Structures
- Suggested Reading
- Chapter-4. Nonstoichiometry in Solids
- 4.1 Thermodynamic Considerations
- 4.1.1 Oxygen Deficient Oxide4.1.2 Metal Deficient Oxides
- 4.2 Classification of Non-stoichiometry
- 4.2.1 Small Deviation from Stoichiometry
- 4.2.2 Large Deviation from Stoichiometry
- 4.3 Superlattice Ordering of Defects
- 4.4 Shear Structure
- Suggested Reading
- Chapter-5. Phase Transition in Solids
- 5.1 Thermodynamic Considerations
- 5.2 Types of Phase Transitions
- 5.2.1 Order-disorder Transformation
- 5.2.2 Martensitic Transition
- 5.2.3 Polymorphic Transformation
- 5.2.4 Recrystallization
- 5.2.5 Polytypes
- 5.3 Phase Rule
- 5.4 Two-Component System5.4.1 Solid-liquid Phase Diagram
- 5.5 Rate of Phase Transition
- 5.6 Sintering
- 5.7 Growing Single Crystals
- 5.7.1 Practical Methods of Growing Crystals
- Suggested Reading
- Chapter-6. Reactions of Solids
- 6.1 Thermal Decomposition
- 6.1.1 Laws of Nucleation and Growth
- 6.1.2 Some Type I Reactions
- 6.1.3 Reaction between Two Solids
- 6.1.4 Improving Solid-Solid Reactions
- 6.2 Diffusion in Solids
- 6.2.1 Atomic Approach
- 6.2.2 Diffusion Equation
- 6.2.3 The Continuum Method
- Suggested Reading