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March's advanced organic chemistry : reactions, mechanisms, and structure.
Seventh Edition integrates advances in organic chemistry and reactions into acclaimed text "Who can hope to be seriously accepted as a member of the organic chemistry community without being in possession of at least one edition of March?"--Chemistry & Industry, from a review of the Si...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2013.
|
| Edición: | 7th edition / |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 100 | 1 | |a Smith, Michael, |d 1946 October 17- | |
| 245 | 1 | 0 | |a March's advanced organic chemistry : |b reactions, mechanisms, and structure. |
| 246 | 3 | 0 | |a Advanced organic chemistry |
| 250 | |a 7th edition / |b Michael B. Smith, Professor of Chemistry. | ||
| 264 | 1 | |a Hoboken : |b Wiley, |c 2013. | |
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 500 | |a Includes index. | ||
| 505 | 0 | |a Localized chemical bonding -- Delocalized chemical bonding -- Bonding weaker than covalent -- Stereochemistry and conformation -- Carbocations, carbanions, free radicals, carbenes, and nitrenes -- Mechanisms and methods of determining them -- Irradiation processes in organic chemistry -- Acids and bases -- Effects of structure and medium on reactivity -- Aliphatic substitution, nucleophilic and organometallic -- Aromatic substitution, electrophilic -- Aliphatic, alkenyl, and alkynyl substitution, electrophilic and organometallic -- Aromatic substitution, nucleophilic and organometallic -- Substitution reactions, radical -- Addition to carbon-carbon multiple bonds -- Addition to carbon-hetero multiple bonds -- Eliminations -- Rearrangements -- Oxidations and reductions -- Appendix A. The literature of organic chemistry -- Appendix B. Classification of reactions by type of compounds synthesized. | |
| 588 | 0 | |a Print version record and CIP data provided by publisher. | |
| 504 | |a Includes bibliographical references (pages 1569-1604) and indexes. | ||
| 520 | |a Seventh Edition integrates advances in organic chemistry and reactions into acclaimed text "Who can hope to be seriously accepted as a member of the organic chemistry community without being in possession of at least one edition of March?"--Chemistry & Industry, from a review of the Sixth Edition Now in its seventh edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry, setting the foundation for organic chemistry theory and practice. Throughout its many editions, readers have relied on its clear, carefully written descriptions of reactions, mechanisms, and structure to plan and execute multi-step synthetic reactions. Offering a comprehensive treatment of organic chemistry, the text explores: Structure of organic compounds, explaining important organic chemistry bonds, fundamental principles of conformation, stereochemistry of organic molecules, and reactive intermediates Principles of mechanisms in organic chemistry, including acids and bases, photochemistry, sonochemistry, microwave irradiation, and the relationship between structure and reactivity Nature, scope, and mechanisms of individual organic reactions This Seventh Edition updates the text to reflect the most recent advances in organic chemistry and organic reactions. More than 5,500 references have been added to guide students to the latest primary, secondary, and review literature. In addition, there's a literature guide to help readers conduct thorough searches of any topic in organic chemistry. With detailed descriptions of organic reactions to guide students through all the stages of planning and performing multi-step synthetic reactions, March's continues to be the textbook of choice for organic chemistry instructors and students around the world. | ||
| 590 | |a Knovel |b ACADEMIC - Chemistry & Chemical Engineering | ||
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Chemistry, Organic. | |
| 650 | 1 | 2 | |a Chemistry, Organic |
| 650 | 2 | 2 | |a Organic Chemistry Phenomena |
| 650 | 4 | |a Chemistry, Organic |x Programmed instruction. | |
| 650 | 4 | |a Chemistry, Organic. | |
| 650 | 4 | |a Chemistry. | |
| 650 | 6 | |a Chimie organique. | |
| 650 | 7 | |a organic chemistry. |2 aat | |
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| 776 | 0 | 8 | |i Print version: |a Smith, Michael, 1946 October 17- |t March's advanced organic chemistry. |b 7th Edition / Michael B. Smith, Professor of Chemistry. |d Hoboken : Wiley, 2013 |z 9780470462591 |w (DLC) 2012027160 |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=1144071 |z Texto completo |
| 880 | 8 | |6 505-00/(S |a 9.C. Quantitative Treatments of the Effect of Structure on Reactivity -- 9.D. Effect of Medium on Reactivity and Rate -- 9.D.i. High Pressure -- 9.D.ii. Water and Other Non-Organic Solvents -- 9.D.iii. Ionic Solvents -- 9.D.iv. Solventless Reactions -- Part II: Introduction -- 10. Aliphatic Substitution, Nucleophilic and Organometallic -- 10.A. Mechanisms -- 10.A.i. The SN2 Mechanism -- 10.A.ii. The SN1 Mechanism -- 10.A.iii. Ion Pairs in the SN1 Mechanism -- 10.A.iv. Mixed SN1 and SN2 Mechanisms -- 10.B. SET Mechanisms -- 10.C. The Neighboring-Group Mechanism -- 10.C.i. Neighboring-Group Participation by π and σ Bonds: Nonclassical Carbocations -- 10.D. The SNi Mechanism -- 10.E. Nucleophilic Substitution at an Allylic Carbon: Allylic Rearrangements -- 10.F. Nucleophilic Substitution at an Aliphatic Trigonal Carbon: The Tetrahedral Mechanism -- 10.G. Reactivity -- 10.G.i. The Effect of Substrate Structure -- 10.G.ii. The Effect of the Attacking Nucleophile -- 10.G.iii. The Effect of the Leaving Group -- 10.G.iv. The Effect of the Reaction Medium -- 10.G.v. Phase-Transfer Catalysis -- 10.G.vi. Influencing Reactivity by External Means -- 10.G.vii. Ambident (Bidentant) Nucleophiles: Regioselectivity -- 10.G.viii. Ambident Substrates -- 10.H. Reactions -- 10.H.i. Oxygen Nucleophiles -- 10.H.ii. Attack by OR at an Alkyl Carbon -- 10.H.iii. Sulfur Nucleophiles -- 10.H.iv. Nitrogen Nucleophiles -- 10.H.v. Halogen Nucleophiles -- 10.H.vi. Carbon Nucleophiles -- 11. Aromatic Substitution, Electrophilic -- 11.A. Mechanisms -- 11.A.i. The Arenium Ion Mechanism -- 11.A.ii. The SE1 Mechanism -- 11.B. Orientation and Reactivity -- 11.B.i. Orientation and Reactivity in Monosubstituted Benzene Rings -- 11.B.ii. The Ortho/Para Ratio -- 11.B.iii. Ipso Attack -- 11.B.iv. Orientation in Benzene Rings with More Than One Substituent. | |
| 880 | 0 | |6 505-00/(S |a March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure -- Contents -- Preface -- Common Abbreviations -- Biographical Statement -- Part I: Introduction -- 1. Localized Chemical Bonding -- 1.A. Covalent Bonding -- 1.B. Multiple Valence -- 1.C. Hybridization -- 1.D. Multiple Bonds -- 1.E. Photoelectron Spectroscopy -- 1.F. Electronic Structures of Molecules -- 1.G. Electronegativity -- 1.H. Dipole Moment -- 1.I. Inductive and Field Effects -- 1.J. Bond Distances -- 1.K. Bond Angles -- 1.L. Bond Energies -- 2. Delocalized Chemical Bonding -- 2.A. Molecular Orbitals -- 2.B. Bond Energies and Distances in Compounds Containing Delocalized Bonds -- 2.C. Molecules that have Delocalized Bonds -- 2.D. Cross-Conjugation -- 2.E. The Rules of Resonance -- 2.F. The Resonance Effect -- 2.G. Steric Inhibition of Resonance and the Influences of Strain -- 2.H. pπ-dπ Bonding. Ylids -- 2.I. Aromaticity -- 2.I.i. Six-Membered Rings -- 2.I.ii. Five, Seven, and Eight-Membered Rings -- 2.I.iii. Other Systems Containing Aromatic Sextets -- 2.J. Alternant and Nonalternant Hydrocarbons -- 2.K. Aromatic Systems with Electron Numbers other than Six -- 2.K.i. Systems of Two Electrons -- 2.K.ii. Systems of Four Electrons: Antiaromaticity -- 2.K.iii. Systems of Eight Electrons -- 2.K.iv. Systems of Ten Electrons -- 2.K.v. Systems of more than Ten Electrons: 4n + 2 Electrons -- 2.K.vi. Systems of more than 10 Electrons: 4n Electrons -- 2.L. Other Aromatic Compounds -- 2.M. Hyperconjugation -- 2.N. Tautomerism -- 2.N.i. Keto-Enol Tautomerism -- 2.N.ii. Other Proton-Shift Tautomerism -- 3. Bonding Weaker Than Covalent -- 3.A. Hydrogen Bonding -- 3.B. π-π Interactions -- 3.C. Addition Compounds -- 3.C.i. Electron Donor-Acceptor Complexes -- 3.C.ii. Crown Ether Complexes and Cryptates -- 3.C.iii. Inclusion Compounds -- 3.C.iv. Cyclodextrins. | |
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