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Aryl diazonium salts : new coupling agents in polymer and surface science /
"This unique book summarizes the current knowledge of the surface and interface chemistry of aryl diazonium salts. It covers fundamental aspects of diazonium chemistry together with theoretical calculations of surface-molecule bonding, analytical methods used for the characterization of aryl la...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Weinheim, Germany :
John Wiley & Sons,
2012.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Matter
- Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts / Jean Pinson
- Aryl₆Surface Bonding: A Density Functional Theory (DFT) Simulation Approach / Nan Shao, Sheng Dai, De-en Jiang
- Patterned Molecular Layers on Surfaces / Alison J Downard, Andrew J Gross, Bradley M Simons
- Analytical Methods for the Characterization of Aryl Layers / Karsten Hinrichs, Katy Roodenko, J̲rg Rappich, Mohamed M Chehimi, Jean Pinson
- Modification of Nano-objects by Aryl Diazonium Salts / Dao-Jun Guo, Fakhradin Mirkhalaf
- Polymer Grafting to Aryl Diazonium-Modified Materials: Methods and Applications / Sarra Gam-Derouich, Samia Mahouche-Chergui, Hatem Ben Romdhane, Mohamed M Chehimi
- Grafting Polymer Films onto Material Surfaces: The One-Step Redox Processes / Guy Deniau, Serge Palacin, Alice Mesnage, Lorraine Tessier
- Electrografting of Conductive Oligomers and Polymers / Jean Christophe Lacroix, Jalal Ghilane, Luis Santos, Gaelle Trippe-Allard, Pascal Martin, Hyacinthe Randriamahazaka
- The Use of Aryl Diazonium Salts in the Fabrication of Biosensors and Chemical Sensors / J Justin Gooding, Guozhen Liu, Alicia L Gui
- Diazonium Compounds in Molecular Electronics / Richard McCreery, Adam Johan Bergren
- Electronic Properties of Si Surfaces Modified by Aryl Diazonium Compounds / Jörg Rappich, Xin Zhang, Karsten Hinrichs
- Non-Diazonium Organic and Organometallic Coupling Agents for Surface Modification / Fetah I Podvorica
- Various Electrochemical Strategies for Grafting Electronic Functional Molecules to Silicon / Dinesh K Aswal, Shankar Prasad Koiry, Shiv Kumar Gupta
- Patents and Industrial Applications of Aryl Diazonium Salts and Other Coupling Agents / James A Belmont, Christophe Bureau, Mohamed M Chehimi, Sarra Gam-Derouich, Jean Pinson
- Index.
- Aryl Diazonium Salts: New Coupling Agents in Polymer and Surface Science; Contents; Preface; List of Contributors; 1: Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts; 1.1: A Brief Survey of the Chemistry and Electrochemistry of Diazonium Salts; 1.2: The Different Methods that Permit Grafting of Diazonium Salts; 1.2.1: Electrochemistry; 1.2.2: Reducing Substrate, Homolytic Dediazonation, Reaction with the Substrate; 1.2.3: Reducing Reagent; 1.2.4: Neutral and Basic Media; 1.2.5: Ultrasonication; 1.2.6: Heating and Microwave; 1.2.7: Mechanical Grafting.
- 1.2.8: Photochemistry1.3: The Different Substrates, Diazonium Salts, and Solvents that Can Be Used; 1.3.1: Substrates; 1.3.2: Diazonium Salts; 1.3.3: Solvents; 1.4: Evidence for the Presence of a Bond between the Substrate and the Organic Layer; 1.4.1: Stability of the Layer; 1.4.2: Spectroscopic Evidence for a Bond; 1.5: From Monolayers to Multilayers; 1.5.1: Monolayers; 1.5.2: Layers of Medium Thickness; 1.5.2.1 Thick Layers; 1.6: Structure and Formation of Multilayers; 1.6.1: Chemical Structure; 1.6.2: The Spatial Structure of the Layers; 1.6.3: Compactness of the Layers.
- 1.6.4: Swelling of the Layer1.6.5: Electron Transfer through the Layers; 1.6.6: The Formation Mechanism of Multilayers; 1.7: Conclusion; References; 2: Aryl-Surface Bonding: A Density Functional Theory (DFT)Simulation Approach; 2.1: Introduction; 2.2: Density Functional Theory; 2.3: Bonding between Aryl and Various Substrates; 2.3.1: On Graphite/Graphene; 2.3.1.1 On the Basal Plane; 2.3.1.2 On the Edges of Graphene; 2.3.2: On Carbon Nanotubes; 2.3.3: On Metal Surfaces; 2.4: Summary and Outlook; Acknowledgments; References; 3: Patterned Molecular Layers on Surfaces.
- 3.1: Methods Based on Scanning Probe Lithography3.1.1: AFM; 3.1.2: SECM; 3.1.3: Spotting; 3.2: Methods Based on Soft Lithography; 3.2.1: Printing; 3.2.2: Molds; 3.2.3: Nanosphere Lithography; 3.3: Methods Based on Lithography; 3.4: Methods Based on Surface-Directed Patterning; 3.4.1: Modification of Si Surfaces; 3.4.2: Modified Electrode Arrays; 3.5: Summary and Conclusions; References; 4: Analytical Methods for the Characterization of Aryl Layers; 4.1: Introduction; 4.2: Scanning Probe Microscopies; 4.3: UV-VIS Spectroscopy: Transmission, Reflection, and Ellipsometry; 4.4: IR Spectroscopy.
- 4.4.1: Transmission Spectroscopy4.4.2: Reflection Spectroscopy; 4.4.3: Infrared Spectroscopic Ellipsometry (IRSE); 4.4.4: IRSE Surface Characterization; 4.4.5: In Situ IR Spectroscopy: ATR and IRSE; 4.5: Raman Spectroscopy and Surface-Enhanced Raman Scattering (SERS); 4.6: X-ray Photoelectron Spectroscopy (XPS); 4.7: X-ray Standing Waves (XSW); 4.8: Rutherford Backscattering; 4.9: Time of Flight Secondary Ion Mass Spectroscopy; 4.10: Electrochemistry; 4.11: Contact Angle Measurements; 4.12: Conclusion; References; 5: Modification of Nano-objects by Aryl Diazonium Salts; 5.1: Introduction; 5.2: Electrochemical Modification of Nano-objects by Reduction of Diazonium Salts.