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Solidification and Crystallization Processing in Metals and Alloys.
Solidification and Crystallization Processing in Metals and Alloys Hasse Fredriksson KTH, Royal Institute of Technology, Stockholm, Sweden Ulla Åkerlind University of Stockholm, Sweden Solidification or crystallization occurs when atoms are transformed from the disordered liquid state to the more o...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2012.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Solidification and Crystallization Processing in Metals and Alloys; Contents; Preface; 1 Thermodynamic Concepts and Relationships; 1.1 Introduction; 1.2 Thermodynamic Concepts and Relationships; 1.2.1 First Law of Thermodynamics. Principle of Conservation of Energy; 1.2.2 Enthalpy; 1.2.3 Second Law of Thermodynamics. Entropy; 1.2.4 Gibbs' Free Energy; 1.2.5 Intensive and Extensive Thermodynamic Quantities; 1.3 Thermodynamics of Single-Component Systems; 1.3.1 Clausius-Clapeyron's Law.
- 1.3.2 Equilibrium between Liquid and Solid Phases. Influence of Pressure and Crystal Curvature on Melting Point1.3.3 Equilibrium between Liquid and Gaseous Phases. Influence of Pressure on Boiling Point. Bubble Formation in Melts; 1.3.4 Molar Gibbs' Free Energy of a Pure Metal; 1.4 Thermodynamics of Multiple-Component Systems; 1.4.1 Partial Molar Thermodynamic Quantities; 1.4.2 Relative Thermodynamic Quantities and Reference States. Relative Partial Molar Thermodynamic Quantities or Partial Molar Quantities of Mixing.
- 1.4.3 Relative Integral Molar Thermodynamic Quantities or Integral Molar Quantities of Mixing1.4.4 Other Thermodynamic Functions and Relationships; 1.5 Thermodynamics of Alloys; 1.5.1 Heat of Mixing; 1.5.2 Ideal and Non-Ideal Solutions; 1.6 Thermodynamics of Ideal Binary Solutions; 1.6.1 Molar Gibbs' Free Energy of Ideal Binary Solutions; 1.7 Thermodynamics of Non-Ideal Binary Solutions; 1.7.1 Activities of Non-Ideal Solutions Raoult's and Henry's Laws; 1.7.2 Excess Quantities of Non-Ideal Solutions; 1.7.3 Molar Gibbs' Free Energies of Non-Ideal Binary Solutions.
- 1.8 Experimental Determination of Thermodynamic Quantities of Binary Alloys1.8.1 Determination of Molar Heat of Mixing of Binary Alloys; 1.8.2 Determination of Partial Molar Gibbs' Free Energy of Mixing of Binary Alloys; Summary; Further Reading; 2 Thermodynamic Analysis of Solidification Processes in Metals and Alloys; 2.1 Introduction; 2.2 Thermodynamics of Pure Metals; 2.2.1 Driving Force of Solidification; 2.3 Thermodynamics of Binary Alloys; 2.3.1 Gibbs' Free Energy of Ideal Binary Solutions; 2.3.2 Gibbs' Free Energy of Non-Ideal Solutions.
- 2.3.3 The Regular-Solution Model. Miscibility Gap in a Regular Solution2.4 Equilibrium Between Phases in Binary Solutions. Phase Diagrams of Binary Alloys; 2.4.1 Gibbs' Phase Rule; 2.4.2 Gibbs' Free Energy Curves for Solid and Liquid Binary Solutions; 2.4.3 The Tangent to Tangent Method to Predict Phases in Binary Solutions; 2.4.4 Calculation of Chemical Potentials from Gibbs' Free Energy Diagrams; 2.4.5 Phase Diagrams of Binary Alloys; 2.4.6 Relationship between Molar Gibbs' Free Energy Curves and Phase Diagrams. Construction of Phase Diagrams; 2.4.7 Influence of Parameters on Phase Diagrams.