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New strategies in chemical synthesis and catalysis /
Providing a comprehensive overview of the essential topics, this book covers the core areas of organic, inorganic, organometallic, biochemical synthesis and catalysis. The authors are among the rising stars in European chemistry, a selection of participants in the 2010 European Young Chemists Award...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Weinheim : Chichester :
Wiley-VCH ; John Wiley [distributor],
2012.
|
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 245 | 0 | 0 | |a New strategies in chemical synthesis and catalysis / |c edited by Bruno Pignataro. |
| 260 | |a Weinheim : |b Wiley-VCH ; |a Chichester : |b John Wiley [distributor], |c 2012. | ||
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
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| 505 | 0 | |6 880-01 |a Front Matter -- Synthetic Methods. Electrospray and Cryospray Mass Spectrometry: From Serendipity to Designed Synthesis of Supramolecular Coordination and Polyoxometalate Clusters / Haralampos N Miras, Leroy Cronin -- Efficient Synthesis of Natural Products Aided by Automated Synthesizers and Microreactors / Shinichiro Fuse, Kazuhiro Machida, Takashi Takahashi -- Chemoselective Reduction of Amides and Imides / Shoubhik Das -- Ionic Ozonides ₆ From Simple Inorganic Salts to Supramolecular Building Blocks / Hanne Nuss, Martin Jansen -- Chemistry and Biological Properties of Amidinoureas: Strategies for the Synthesis of Original Bioactive Hit Compounds / Daniele Castagnolo -- Catalysis. DNA Catalysts for Synthetic Applications in Biomolecular Chemistry / Claudia H̲bartner, P I Pradeepkumar -- Iron-Catalyzed Csp ₆ H Oxidation with HO: Converting a Radical Reaction into a Selective and Efficient Synthetic Tool / Laura G̤mez -- Hydrogen Bonds as an Alternative Activation / Eugenia Marqǔs-L̤pez, Raquel P Herrera -- Electrosynthesized Structured Catalysts for H Production / Patricia Benito, Francesco Basile, Giuseppe Fornasari, Marco Monti, Erika Scavetta, Domenica Tonelli, Angelo Vaccari -- Microkinetic Analysis of Complex Chemical Processes at Surfaces / Matteo Maestri -- Synthetic Potential behind Gold-Catalyzed Redox Processes / Cristina Nevado, Teresa de Haro -- Transition-Metal Complexes in Supported Liquid Phase and Supercritical Fluids ₆ A Beneficial Combination for Selective Continuous-Flow Catalysis with Integrated Product Separation / Ulrich Hintermair, Tamilselvi Chinnusamy, Walter Leitner -- Combinatorial and Chemical Biology. Inhibiting Pathogenic Protein Aggregation: Combinatorial Chemistry in Combating Alpha-1 Antitrypsin Deficiency / Yi-Pin Chang -- Synthesis and Application of Macrocycles Using Dynamic Combinatorial Chemistry / Vittorio Saggiomo -- Toward Tomorrow's Drugs: The Synthesis of Compound Libraries by Solid-Phase Chemistry / Dagmar C Kapeller, Stefan Br̃se -- Index. | |
| 500 | |a Includes index. | ||
| 588 | 0 | |a Print version record. | |
| 520 | |a Providing a comprehensive overview of the essential topics, this book covers the core areas of organic, inorganic, organometallic, biochemical synthesis and catalysis. The authors are among the rising stars in European chemistry, a selection of participants in the 2010 European Young Chemists Award competition, and their contributions deal with most of the frontier issues in chemical synthesis. They give an account of the latest research results in chemistry in Europe, as well as the state of the art in their field of research and the outlook for the future. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Chemical reactions. | |
| 650 | 0 | |a Catalysis. | |
| 650 | 2 | |a Catalysis | |
| 650 | 6 | |a Catalyse. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Catalysis |2 fast | |
| 650 | 7 | |a Chemical reactions |2 fast | |
| 700 | 1 | |a Pignataro, Bruno. | |
| 776 | 0 | 8 | |i Print version: |t New strategies in chemical synthesis and catalysis. |d Weinheim : Wiley-VCH ; Chichester : John Wiley [distributor], 2012 |z 9783527330904 |w (OCoLC)773431454 |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=915870 |z Texto completo |
| 880 | 0 | 0 | |6 505-01/(S |g Machine generated contents note: |g pt. I |t Synthetic Methods -- |g 1. |t Electrospray and Cryospray Mass Spectrometry: From Serendipity to Designed Synthesis of Supramolecular Coordination and Polyoxometalate Clusters / |r Leroy Cronin -- |g 1.1. |t Introduction -- |g 1.2. |t Background to ESI-MS -- |g 1.2.1. |t Background to CSI-MS -- |g 1.3. |t Application of High-Resolution ESI-MS and CSI-MS to Polyoxometalate Cluster Systems -- |g 1.3.1. |t Probing Protonation Versus Heteroatom Inclusion with ESI -- |g 1.3.2. |t Solution Identification of Functionalized POMs -- |g 1.3.3. |t Solution Identification of New Isopolyoxotungstates and Isopolyoxoniobates -- |g 1.3.4. |t Solution Identification and Isolation of Mixed-Metal/Valence POMs with CSI-MS -- |g 1.3.5. |t Mixed-Metal/Valence Hetero-POMs V2 [⊂] {M17V1} -- |g 1.3.6. |t Periodate-Containing POMs -- |g 1.3.7. |t Probing the Formation of POM-Based Nano-Structures -- |g 1.3.8. |t Mechanistic Insights into POM Self-Assembly Using ESI- and CSI-MS -- |g 1.4. |t Species Identification and Probing Structural Transformations in Multi-Metallic Systems -- |g 1.5. |t Future Challenges and Conclusions -- |t References -- |g 2. |t Efficient Synthesis of Natural Products Aided by Automated Synthesizers and Microreactors / |r Takashi Takahashi -- |g 2.1. |t Efficient Synthesis of Natural Products Aided by Automated Synthesizers -- |g 2.1.1. |t Process of Automating the Supply of Synthetic Intermediates -- |g 2.1.2. |t Efficient Synthesis of a Cyanohydrin Key Intermediate for Taxol Using Automated Synthesizers -- |g 2.1.3. |t Efficient Synthesis of a Cyclic Ether Key Intermediate for Nine-Membered Masked Enediyne, Using an Automated Synthesizer -- |g 2.1.4. |t List of Reactions Successfully Performed in Automated Synthesizers -- |g 2.2. |t Continuous-Flow Synthesis of Vitamin D3 -- |g 2.3. |t Conclusions -- |t Acknowledgments -- |t References -- |g 3. |t Chemoselective Reduction of Amides and Imides / |r Shoubhik Das -- |g 3.1. |t Introduction -- |g 3.2. |t Reduction of Tertiary Amides -- |g 3.3. |t Reduction of Secondary Amides -- |g 3.4. |t Dehydration of Primary Amides -- |g 3.5. |t Reduction of Imides -- |g 3.6. |t Conclusion -- |t Acknowledgment -- |t References -- |g 4. |t Ionic Ozonides -- From Simple Inorganic Salts to Supramolecular Building Blocks / |r Martin Jansen -- |g 4.1. |t Forgotten Oxygen Anion -- |g 4.2. |t Synthesis of Ionic Ozonides -- |g 4.3. |t Structural Variety of Ionic Ozonides -- |g 4.3.1. |t Simple Binary and Pseudo-Binary Ozonides -- |g 4.3.2. |t Cs5([12]crown-4)2(O3)5 -- from Simple Salts to Supramolecular Building Blocks -- |g 4.4. |t Magnetic Properties -- |g 4.5. |t Conclusions and Perspectives -- |t References -- |g 5. |t Chemistry and Biological Properties of Amidinoureas: Strategies for the Synthesis of Original Bioactive Hit Compounds / |r Daniele Castagnolo -- |g 5.1. |t Amidinoureas: an Introduction -- |g 5.2. |t Amidinoureas in Chemistry -- |g 5.3. |t Synthetic Strategies for the Preparation of Amidinoureas -- |g 5.3.1. |t Hydrolysis of Biguanides -- |g 5.3.2. |t Reaction of Guanidines with Isocyanates -- |g 5.3.3. |t Hydrolysis of Cyanoguanidines -- |g 5.3.4. |t Reaction of Acyl-S-Methylisothiourea with Amines -- |g 5.3.5. |t Reaction of Di-Boc-Guanidines with Amines -- |g 5.4. |t Macrocyclic Amidinoureas -- |g 5.4.1. |t Guanylated Polyamines -- |g 5.4.2. |t Conversion of Di-Boc-Guanylated Diamines into Amidinoureas -- |g 5.4.3. |t Synthesis of Cyclic Amidinoureas -- |g 5.4.4. |t Synthesis of Macrocyclic Amidinoureas from Di-Boc-Monoguanylated Triamines -- |g 5.4.5. |t Biological Properties of Cyclic Amidinoureas -- |g 5.5. |t Perspectives -- |t Acknowledgments -- |t References -- |g pt. II |t Catalysis -- |g 6. |t DNA Catalysts for Synthetic Applications in Biomolecular Chemistry / |r P.I. Pradeepkumar -- |t Abbreviations -- |g 6.1. |t Introduction -- |g 6.2. |t In vitro Selection of Deoxyribozymes -- |g 6.3. |t Scope of DNA-Catalyzed Reactions -- |g 6.4. |t Synthetic Applications of RNA-Cleaving Deoxyribozymes -- |g 6.5. |t DNA-Catalyzed Linear Ligation of RNA -- |g 6.6. |t DNA-Catalyzed Synthesis of 2',5'-Branched Nucleic Acids -- |g 6.6.1. |t 2',5'-Branched RNA -- |g 6.6.2. |t 2',5'-Branched Nucleic Acids Containing RNA as Scaffold and DNA as Adaptor -- |g 6.6.3. |t 2',5'-Branched DNA -- |g 6.6.4. |t 2',5'-Branched Nucleic Acids Containing DNA as Scaffold and RNA as "Adaptor" -- |g 6.7. |t DNA-Catalyzed Synthesis of Nucleopeptide Conjugates -- |g 6.8. |t Mechanistic Aspects of DNA Catalysis -- |g 6.9. |t Conclusions and Outlook -- |t References -- |g 7. |t Iron-Catalyzed Csp3-H Oxidation with H2O2: Converting a Radical Reaction into a Selective and Efficient Synthetic Tool / |r Laura Gomez -- |g 7.1. |t Introduction and Scope -- |g 7.2. |t Environmentally Benign C-H Oxidation -- |g 7.3. |t Inspiration from Nature -- |g 7.4. |t Mechanistic Considerations -- |g 7.5. |t Bioinspired C-H Oxidation Catalysts -- |g 7.5.1. |t Porphyrinic Catalyst -- |g 7.5.2. |t Non-porphyrinic Mononuclear Iron Catalysts -- |g 7.6. |t Perspectives -- |t References -- |g 8. |t Hydrogen Bonds as an Alternative Activation / |r Raquel P. Herrera -- |g 8.1. |t Introduction -- |g 8.1.1. |t Chiral Thiourea/Urea Organocatalysts -- |g 8.2. |t Thiourea Catalysts -- |g 8.2.1. |t Friedel-Crafts Alkylation Reaction -- |g 8.2.2. |t Michael Addition Reactions -- |g 8.2.2.1. |t Michael Addition Reaction of N, N-Dialkylhydrazones to Nitroalkenes -- |g 8.2.2.2. |t Michael Addition Reaction of Formaldehyde N, N-Dialkylhydrazones to β, γ-Unsaturated α-Keto Esters -- |g 8.2.2.3. |t Hydrophosphonylation Reaction of Nitroalkenes -- |g 8.2.3. |t Aza-Henry Reaction -- |g 8.3. |t Conclusions -- |t Acknowledgments -- |t References -- |g 9. |t Electrosynthesized Structured Catalysts for H2 Production / |r Angelo Vaccari -- |g 9.1. |t Introduction -- |g 9.2. |t Preparation of Structured Catalysts -- |g 9.3. |t Electrosynthesis -- |g 9.4. |t Electrosynthesis of Hydrotalcite-Type Compounds -- |g 9.4.1. |t Experimental -- |g 9.4.2. |t Ni/Al and Rh/Mg/Al HT Compounds on FeCrAlloy Foams -- |g 9.4.3. |t Catalysts -- |g 9.4.4. |t Steam Reforming and Catalytic Partial Oxidation of Methane -- |g 9.5. |t Summary and Outlook -- |t References -- |g 10. |t Microkinetic Analysis of Complex Chemical Processes at Surfaces / |r Matteo Maestri -- |t Notation -- |t Greek letters -- |g 10.1. |t Introduction -- |g 10.2. |t Time and Length Scales in Heterogeneous Catalysis -- |g 10.3. |t Hierarchical Multiscale Approach for Microkinetic Model Development -- |g 10.3.1. |t Microkinetic Model Development -- |g 10.3.1.1. |t Prediction of Activation Energies Using the UBI-QEP Semiempirical Method -- |g 10.3.1.2. |t First-Principles Assessment of the UBI-QEP Semiempirical Method -- |g 10.3.2. |t Meso-Scale and Macroscale: Reaction and Reactor Engineering -- |g 10.3.3. |t Hierarchical Multiscale Refinement of the Microkinetic Model -- |g 10.4. |t Show Case: Microkinetic Analysis of CH4 Partial Oxidation on Rh -- |g 10.4.1. |t Microkinetic Model for the Conversion of CH4 to Syngas -- |g 10.4.2. |t Microkinetic Analysis of Isothermal CPOX Data in Annular Reactor -- |g 10.4.3. |t Microkinetic Analysis of Autothermal CPOX Data on Foams -- |g 10.5. |t Conclusions -- |t Acknowledgments -- |t References -- |g 11. |t Synthetic Potential behind Gold-Catalyzed Redox Processes / |r Teresa de Haro -- |g 11.1. |t Introduction -- |g 11.2. |t Gold-Catalyzed Reactions Involving Oxygen Functionalities -- |g 11.2.1. |t Oxidation of Alkanes -- |g 11.2.2. |t Oxidation of Alcohols to Carbonyl Compounds -- |g 11.2.3. |t Oxidation of Alkenes -- |g 11.2.4. |t Oxidation of Sulfides to Sulfoxides -- |g 11.2.5. |t Oxidation of Gold-Carbene Intermediates -- |g 11.2.6. |t Substrates as Internal Oxidants -- |g 11.3. |t Gold-Catalyzed Reactions Involving Nitrogen Functionalities -- |g 11.4. |t Gold-Catalyzed Reactions Involving C-C Bond Formation -- |g 11.4.1. |t Ethynylation Reactions -- |g 11.4.2. |t Homocoupling Reactions -- |g 11.4.3. |t Cross-Coupling Involving B and Si Reagents -- |g 11.5. |t Gold-Catalyzed Reactions Involving Alkene Difunctionalization -- |g 11.6. |t Gold-Catalyzed Reactions Involving Halogen Functionalities -- |g 11.7. |t Summary and Outlook -- |t References -- |g 12. |t Transition-Metal Complexes in Supported Liquid Phase and Supercritical Fluids -- A Beneficial Combination for Selective Continuous-Flow Catalysis with Integrated Product Separation / |r Walter Leitner -- |g 12.1. |t Strategies for Catalyst Immobilization Using Permanent Separation Barriers -- |g 12.2. |t Supported Liquid-Phase Catalysts Based on Organic Solvents (SLP) -- |g 12.3. |t Supported Aqueous-Phase Catalysts (SAP) -- |g 12.4. |t Supported Ionic Liquid-Phase Catalysts (SILP) -- |g 12.4.1. |t Synthetic Methods -- |g 12.4.2. |t Characteristics -- |g 12.4.3. |t Gas-Phase Applications -- |g 12.4.4. |t Liquid-Phase Applications -- |g 12.5. |t Supported Liquid-Phase Catalysts and Supercritical Fluids |
| 880 | 0 | 0 | |t -- |g 12.6. |t Conclusion -- |t References -- |g pt. III |t Combinatorial and Chemical Biology -- |g 13. |t Inhibiting Pathogenic Protein Aggregation: Combinatorial Chemistry in Combating Alpha-1 Antitrypsin Deficiency / |r Yi-Pin Chang -- |g 13.1. |t Introduction -- |g 13.2. |t α-Antitrypsin Deficiency -- |g 13.2.1. |t α-Antitrypsin and Serpin -- |g 13.2.2. |t Polymerization Pathways of Serpins -- |g 13.2.3. |t Emerging Therapeutic Strategies -- |g 13.3. |t Targeting the s4A Site with the Peptide Annealing Method -- |g 13.3.1. |t Functional and Structural Studies of RCLs -- |g 13.3.2. |t Smaller RCL-Derived and Non-RCL Serpin-Binding Peptides -- |g 13.4. |t Expanding the Molecular Diversity -- |g 13.4.1. |t Alanine Scanning, Truncation, and D-Amino Acid Scanning Libraries -- |g 13.4.2. |t β-Strand-Directed Library -- |g 13.4.3. |t Positional Scanning Library -- |g 13.5. |t Characterization of the Combinatorially Selected Peptide -- |g 13.5.1. |t Validation of the Binding by SPR -- |g 13.5.2. |t Cytotoxicity of the Identified Peptide and the Proposed Structure of the Binary Complex -- |g 13.6. |t Conclusion and Outlook -- |t Acknowledgments -- |t References -- |g 14. |t Synthesis and Application of Macrocycles Using Dynamic Combinatorial Chemistry / |r Vittorio Saggiomo -- |g 14.1. |t Supramolecular Chemistry -- |g 14.2. |t Dynamic Combinatorial Chemistry -- |g 14.2.1. |t Next Step: Applications. |
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