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Modern Gold Catalyzed Synthesis.
With its impressive features, gold has added another facet to organic catalysis. Focusing on homogeneous catalysis this book also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, this monograph goes on to...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
John Wiley & Sons,
2012.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Further Reading; Title Page; Copyright; List of Contributers; Chapter 1: Hydrochlorination of Acetylene Catalyzed by Gold; 1.1 Introduction; 1.2 Reactions of Alkynes Using Gold Chloride as Catalyst; 1.3 The Correlation of E° with the Activity of Gold for the Hydrochlorination of Acetylene; 1.4 Central Role of Au3+ and Regeneration of Au/C Catalysts; 1.5 Reaction Mechanism of Alkynes Over Au/C Catalysts; 1.6 Chemical Origin of the E° Correlation and General Remarks; 1.7 Commercial Processes and Economic Aspects of Vinyl Chloride Monomer Manufacture; References.
- Chapter 2: Gold-Catalyzed Reduction Reactions2.1 Introduction; 2.2 Hydrogenation of Multiple C=C Bonds. Role of the Gold Oxidation State; 2.3 Hydrogenation of a, ß-Unsaturated Aldehydes; 2.4 Hydrogenation of Substituted Nitroaromatic Compounds; References; Chapter 3: Gold-Catalyzed Benzannulations: Asao-Yamamoto Benzopyrylium Pathway; 3.1 Introduction; 3.2 Acetylenic Compounds as 2p Systems; 3.3 Enols as 2p Systems; 3.4 Enol Ethers as 2p Systems; 3.5 Benzynes as 2p Systems; 3.6 Synthesis of Phthalazine Derivatives.
- 3.7 Application to the Synthesis of Angucyclinone Antibiotics and Other Applications in Total Synthesis3.8 Copper-Catalyzed Benzannulations; 3.9 Conclusion; References; Chapter 4: Gold-Catalyzed Reactions of Propargyl Esters, Propargyl Alcohols, and Related Compounds; 4.1 Introduction and Extent of This Chapter; 4.2 Propargyl Esters; 4.3 Propargyl Ethers; 4.4 Propargyl Alcohols; 4.5 Propargyl Amines; 4.6 Propargyl Carbonates, Amides, and Carbamates; 4.7 Other Propargyl Substitution Patterns; 4.8 Conclusion; Reagent Abbreviations; References; Chapter 5: Intramolecular Hydroarylation of Alkynes.
- 5.1 Introduction5.2 Intramolecular Reactions of Arenes with Alkynes; 5.3 Intramolecular Reactions of Electron-Rich Heteroarenes with Alkynes; 5.4 Conclusion and Outlook; Acknowledgments; References; Chapter 6: Gold-Alkyne Complexes; 6.1 Introduction; 6.2 Description of the M-p-Bond Interaction in Alkene and Alkyne Complexes; 6.3 Gold(0) Complexes; 6.4 Gold(I) Complexes; 6.5 Gold(III) complexes; 6.6 Theoretical Studies; References; Chapter 7: Gold-Alkene Complexes; 7.1 Introduction; 7.2 Gold(0) Derivatives; 7.3 Gold(I) Complexes; 7.4 Gold(III) Complexes; 7.5 Theoretical Studies; References.
- Chapter 8: Hydration and Hydroalkoxylation of CC Multiple Bonds8.1 Historical Perspective; 8.2 Gold Catalysts; 8.3 Hydration and Hydroalkoxylation of CC Triple Bonds (Alkynes); 8.4 Hydration and Hydroalkoxylation of CC Double Bonds (Allenes and Alkenes); References; Chapter 9: Gold-Catalyzed Aldol and Related Reactions; 9.1 The Gold-Catalyzed Aldol Reaction; 9.2 Related Reactions; Acknowledgement; References; Chapter 10: Gold-Catalyzed Oxidation Reactions: Oxidation of Alkenes; 10.1 Introduction; 10.2 Epoxidation Reactions; 10.3 Aziridination Reactions.