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Anion Coordination Chemistry.
Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recent approaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of an...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
John Wiley & Sons,
2012.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Related Titles; Title Page; Copyright; Preface; List of Contributors; Chapter 1: Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; Chapter 2: Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.3 Molecular Recognition and Selectivity.
- 2.4 Enthalpic and Entropic Contributions in Anion CoordinationReferences; Chapter 3: Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.5 Monocycles; 3.6 Cryptands; 3.7 Transition-Metal-Assisted Ligands; 3.8 Lewis Acid Ligands; 3.9 Conclusion; 3.10 Acknowledgments; References; Chapter 4: Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.3 Design and Synthesis of Amide Receptors; References; Chapter 5: Template Synthesis.
- 5.1 Introductory Remarks5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; Chapter 6: Anion-p Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction; 6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions); 6.4 Influence of Other Noncovalent Interactions on the Anion-p Interaction.
- 6.5 Experimental Examples of Anion-p Interactions in the Solid State and in Solution6.6 Concluding Remarks; References; Chapter 7: Receptors for Biologically Relevant Anions; 7.1 Introduction; 7.2 Phosphate Receptors; 7.3 Carboxylate Receptors; 7.4 Conclusion; References; Chapter 8: Synthetic Amphiphilic Peptides that Self-Assemble to Membrane-Active Anion Transporters; 8.1 Introduction and Background; 8.2 Biomedical Importance of Chloride Channels; 8.3 The Development of Synthetic Chloride Channels; 8.4 Approaches to Synthetic Chloride Channels.
- 8.5 The Development of Amphiphilic Peptides as Anion Channels8.6 Structural Variations in the SAT Modular Elements; 8.7 Conclusions; Acknowledgments; References; Chapter 9: Anion Sensing by Fluorescence Quenching or Revival; 9.1 Introduction; 9.2 Anion Recognition by Dynamic and Static Quenching of Fluorescence; 9.3 Fluorescent Sensors Based on Anthracene and on a Polyamine Framework; 9.4 Turning on Fluorescence with the Indicator Displacement Approach; References; Index.