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Polymer initiators /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Nova Science Publishers, Inc.,
[2011]
|
| Colección: | Biochemistry research trends series.
Polymer science and technology series (Nova Science Publishers) |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- POLYMER INITIATORS ; POLYMER INITIATORS ; CONTENTS ; PREFACE ; INITIATORS FOR ANIONIC POLYMERIZATION: OLD AND NEW DEVELOPMENTS ; ABSTRACT ; 1. INTRODUCTION ; 2. THE INITIATION PROCESS IN ANIONIC POLYMERIZATION ; 2.1. Living Polymerizations: A Brief Introduction ; 2.2. Anionic Living Polymerization ; 3. MONOFUNCTIONAL INITIATORS ; 3.1. Initiation by Using Alkali Metals ; 3.2 Anionic Living Polymerization by Using Alkali Metals/Aromatic Hydrocarbon Complexes ; 3.3. Anionic Living Polymerization by Using Organometallic Initiators ; 3.3.1. Aryl-Alkali Initiators ; 3.3.2. Alkyllithium Initiators.
- 3.3.3. Alkoxy-Alkali Metal Initiators 3.3.4. Silyl Lithium Initiators ; 3.3.5. Mixed Organometallic Initiators ; 3.4. Metal Free Initiators ; 3.4.1. "Onium" Salts in Coordinated Systems ; 3.5. Functionalization Reactions with Monofunctional Initiators ; 3.5.1. DPE Derivatives ; 3.5.2. Silyl Halides Derivatives ; 4. MULTIFUNCTIONAL INITIATORS ; 5. NEW INITIATORS FOR THE MOST COMMON ANIONIC POLYMERIZABLE MONOMERS ; 5.1. Styrene and Styrene Derivatives ; 5.2. Dienes ; 5.3. Acrylates and Their Derivatives; 5.4. Cyclic Monomers ; 6. CONCLUDING REMARKS ; ACKNOWLEDGMENTS ; REFERENCES.
- ADVANCED ORGANOCOBALT INITIATORS OF RADICAL POLYMERIZATION: CURRENT STATE AND POTENTIAL APPLICATIONS ABSTRACT ; INTRODUCTION ; THE INITIATORS ; PREPARATION ; Template Synthesis [2-5], 4-6] ; Ligand Exchange ; Ligand Modification ; Counterion Exchange ; STRUCTURE, CHARACTERIZATION AND ANALYSIS; RELATED REACTIVITY ASPECT: HOMOLYTIC DECOMPOSITION ; PhpH-Dependence of the Rate and Mechanism ; Features of RCo. S Functionalized at Alkyl Ligands ; POLYMERIZATIONS ; In Emulsion ; Decomposition of RCo. S s Under Conditions Aproximated to Those of Emulsion Polymerization.
- Kinetic Regularities of Styrene Polymerization Initiated by RCo.sS Polymerization of (Meth) Acrylic Monomers ; Vinyl Acetate Polymerization ; Isoprene with Styrene Copolymerization; Copolymerization of Acrylonitrile with Styrene and Isoprene ; In Other Media ; CONCLUSION ; REFERENCES ; SURFACE-INITIATED ATRP AS A VERSATILE METHOD TO HYBRID MATERIALS ; 1. INTRODUCTION ; 2. MECHANISM OF ATOM TRANSFER RADICAL POLYMERIZATION ; 3. DIFFERENT ATRP INITIATION STRATEGIES ; 3.1. Reverse ATRP ; 3.2. SR and NI ATRP ; 3.3. AGET/ARGET ATRP ; 3.4. SI-ARGET ATRP ; 3.5. ICAR.
- 4. SURFACE-ATTACHABLE ATRP INITIATORS 5. IMMOBILIZATION OF ATRP INITIATORS ; 5.1. Immobilization of ATRP Initiators onto Reactive Substrates ; 5.1.1. Initiators for Functionalizing Surface OH Groups ; Silicone Dioxide; Inert Silicon(Dioxide) Substrates; 5.1.2. Initiators for Nonoxide Metallic and Semiconductor Surfaces; 5.1.3. ATRP Initiators for Carbon Substrates ; 5.1.4. Immobilization Strategies for Polymeric Surfaces ; Inert Polymeric Surfaces ; Functional/Reactive Polymeric Surfaces ; Biopolymers ; 6. PRACTICAL APPLICATION OF THE SI-ATRP BASED HYBRID MATERIALS.