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Solvent Extraction : Classical and Novel Approaches.

The main challenge in modern solvent extraction separation is that most techniques are mainly empirical, specific and particular for narrow fields of practice and require a large degree of experimentation. ThisÈconcise and modernÈbook provides aÈcomplete overview of both solvent extraction separatio...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Kislik, Vladimir S, I.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Burlington : Elsevier Science, 2011.
Temas:
Acceso en línea:Texto completo

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245 1 0 |a Solvent Extraction :  |b Classical and Novel Approaches. 
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505 0 |a Front Cover; Solvent Extraction: Classical and Novel Approaches; Copyright; Contents; Preface; Introduction; References; Part I -- Conventional (Classical) Principles and Practice of Solvent Extraction; Chapter 1 -- Modern (Classical) Fundamental Principles of Solvent Extraction; 1. Introduction; 2. Solvent Extraction By Solvation; 3. Solvent Extraction with Chemical Reactions (By Complexation); 4. Driving Forces of Solvent Extraction; 5. Influence of Kinetics Factors; 6. Selectivity; 7. Factors Affecting Extraction Process; 8. Module Design Considerations. 
505 8 |a 9. Experimental Determination of Distribution Ratios10. Summarizing Remarks; References; Chapter 2 -- Principles of Solvent Extraction of Organic and Mineral Acids; 1. Introduction; 2. Extraction of Acids by Carbon-Bonded Oxygen-Donor Extractants and Substituted Hydrocarbon Solvents; 3. Phosphorus-bonded Oxygen Donor Extractants; 4. Aliphatic Amine Extractants; 5. Extraction of Strong (Inorganic) Acids; 6. Summarizing Remarks; References; Chapter 3 -- Chemistry of Metal Solvent Extraction; 1. Introduction; 2. Metal Extraction by Cation Exchangers (Acidic Extractants). 
505 8 |a 3 .Metal Extraction by Anion Exchangers (Ion Pair Formation)4. Extraction Through Formation of H-Bonding and Solvating Complexes; 5. Extraction Through Mixed Complex Formation; 6. Extractable Complexation of Monovalent Metals; 7. Extraction with Aqueous Biphasic Systems; References; Chapter 4 -- Engineering Development of Solvent Extraction Processes; 1. Introduction; 2. Extraction Stage; 3 .Stripping Organic Solutions; 4 .Extraction Efficiency; 5 .Equipment Design For Continuous Extraction-Stripping Processes; 6. Solvent Losses; 7. Economical Considerations. 
505 8 |a 8. Problems With Scale-Up To Industrial SystemsReferences; Chapter 5 -- Examples of Application of Solvent Extraction Techniques in Chemical, Radiochemical, Biochemical, Pharmaceutical, Analytical Separations, andWastewater Treatment; 1. Introduction; 2. Extraction in Hydrometallurgy (Metals Extraction); 3. Solvent Extraction in Nuclear Chemistry and Technology; 4. Solvent Extraction in Analytical Chemistry; 5. Application of Solvent Extraction in Biochemical and Pharmaceutical Separations; 6. Application of Solvent Extraction in Organic and Biofuels Separation. 
505 8 |a 7. Solvent Extraction in Recovery of Waste and Wastewater TreatmentReferences; Part II -- Novel Competitive Complexation/Solvation Theory (CCST) of Solvent Extraction: Principles and Practice; Chapter 6 -- Backgrounds of the Competitive Complexation/Solvation Theory of Solvent Extraction; 1. Introduction; 2. Complexation Through the H-Bonding and Proton Transfer; 3. Distribution Isotherm; 4. Modified Competitive Preferential Solvation Theory; 5. Electronic Acid-Base Theory and Amphoterity; 6. Aggregation; References. 
505 8 |a Chapter 7 -- Competitive Complexation/Solvation Theory of Solvent Extraction: General Mechanisms and Kinetics. 
520 |a The main challenge in modern solvent extraction separation is that most techniques are mainly empirical, specific and particular for narrow fields of practice and require a large degree of experimentation. ThisÈconcise and modernÈbook provides aÈcomplete overview of both solvent extraction separation techniques andẗhe novel and unified competitive complexation/solvation theory. This novel and unified technique presented in the book provides a key forä preliminary quantitativeÈprediction ofÈsuitable extraction systemsẅithout experimentation, thus savin. 
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