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Models for Bonding in Chemistry.
A readable little book assisting the student in understanding, in a nonmathematical way, the essentials of the different bonds occurring in chemistry. Starting with a short, self-contained, introduction, Chapter 1 presents the essential elements of the variation approach to either total or second-or...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
John Wiley & Sons,
2011.
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| Edición: | 2nd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title page; Copyright; Dedication; Preface; 1: Mathematical Foundations; 1.1 MATRICES AND SYSTEMS OF LINEAR EQUATIONS; 1.2 PROPERTIES OF EIGENVALUES AND EIGENVECTORS; 1.3 VARIATIONAL APPROXIMATIONS; 1.4 ATOMIC UNITS; 1.5 THE ELECTRON DISTRIBUTION IN MOLECULES; 1.6 EXCHANGE-OVERLAP DENSITIES AND THE CHEMICAL BOND; Part 1: Short-range Interactions; 2: The Chemical Bond; 2.1 AN ELEMENTARY MOLECULAR ORBITAL MODEL; 2.2 BOND ENERGIES AND PAULI REPULSIONS IN HOMONUCLEAR DIATOMICS; 2.3 MULTIPLE BONDS; 2.4 THE THREE-CENTRE DOUBLE BOND IN DIBORANE; 2.5 THE HETEROPOLAR BOND.
- 2.6 STEREOCHEMISTRY OF POLYATOMIC MOLECULES2.7 sp-HYBRIDIZATION EFFECTS IN FIRST-ROW HYDRIDES; 2.8 DELOCALIZED BONDS; 2.9 APPENDICES; 3: An Introduction to Bonding in Solids; 3.1 THE LINEAR POLYENE CHAIN; 3.2 THE CLOSED POLYENE CHAIN; 3.3 A MODEL FOR THE ONE-DIMENSIONAL CRYSTAL; 3.4 ELECTRONIC BANDS IN CRYSTALS; 3.5 INSULATORS, CONDUCTORS, SEMICONDUCTORS AND SUPERCONDUCTORS; 3.6 APPENDIX: THE TRIGONOMETRIC IDENTITY; Part 2: Long-Range Interactions; 4: The van der Waals Bond; 4.1 INTRODUCTION; 4.2 ELEMENTS OF RAYLEIGH-SCHRÖDINGER (RS)PERTURBATION THEORY; 4.3 MOLECULAR INTERACTIONS.
- 4.4 THE TWO-STATE MODEL OF LONG-RANGE INTERACTIONS4.5 THE van der WAALS INTERACTIONS; 4.6 THE C6 DISPERSION COEFFICIENT FOR THE H--H INTERACTION; 4.7 THE van der WAALS BOND; 4.8 THE KEESOM INTERACTION; 5: The Hydrogen Bond; 5.1 A MOLECULAR ORBITAL MODEL OF THE HYDROGEN BOND; 5.2 ELECTROSTATIC INTERACTIONS AND THE HYDROGEN BOND; 5.3 THE ELECTROSTATIC MODEL OF THE HYDROGEN BOND; 5.4 THE Rg-HF HETERODIMERS; References; Author Index; Subject Index.