Phosphorus(III) ligands in homogeneous catalysis : design and synthesis /

"Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the ackn...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Kamer, Paul
Otros Autores: Leeuwen, P. W. N. M. van (Piet W. N. M.)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Chichester, West Sussex, United Kingdom : John Wiley & Sons, Ltd., 2012.
Temas:
Phosphorus compounds.
Ligands.
Catalysis.
Chemistry.
Physical Sciences & Mathematics.
Inorganic Chemistry.
Phosphore > Composés.
Catalyse.
TECHNOLOGY & ENGINEERING > Material Science.
Catalysis
Ligands
Phosphorus compounds
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References.

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