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The Pauson-Khand reaction : scope, variations, and applications /
The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones. The importance of this reaction originates from its high value in transforming simpl...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, N.J. :
John Wiley & Sons,
2012.
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| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 245 | 0 | 4 | |a The Pauson-Khand reaction : |b scope, variations, and applications / |c edited by Ramón Ríos Torres. |
| 260 | |a Hoboken, N.J. : |b John Wiley & Sons, |c 2012. | ||
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
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| 504 | |a Includes bibliographical references and index. | ||
| 588 | 0 | |a Print version record and CIP data provided by publisher. | |
| 505 | 0 | |6 880-01 |a Front Matter -- The Pauson-Khand Reaction 6 an Introduction / William J Kerr -- The Mechanism of the Pauson-Khand Reaction: Hypothesis, Experimental Facts, and Theoretical Investigations / Xacobe C Cambeiro, Miquel A Peric̉s -- Non Chiral Pauson-Khand Reaction / Takanori Shibata -- Diastereoselective Pauson-Khand Reaction using Chiral Pool Techniques (Chiral Substrates) / Martin Kamlar, Jan Vesely, Ramon Rios Torres -- Asymmetric Intra- and Intermolecular Pauson-Khand Reactions: The Chiral Auxiliary Approach / Albert Moyano -- The Enantioselective Pauson-Khand Reaction / Agust̕ Lled̤, Xavier Verdaguer, Antoni Riera -- Recent Advancement of Catalytic Pauson-Khand-type Reactions / Fuk Loi Lam, Hang Wai Lee, Jun Wang, Fuk Yee Kwong -- Recent Adventures with the Pauson-Khand Reaction in Total Synthesis / Scott G Van Ornum, Sarah Hoerner, James M Cook -- Heterogeneous Catalytic Pauson-Khand Reaction / Young Keun Chung -- Other Transition Metal-Mediated Cyclizations Leading to Cyclopentenones / Ramon Rios Torres, Jan Vesely -- Index. | |
| 520 | |a The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones. The importance of this reaction originates from its high value in transforming simple components into the synthetically useful cyclopentenone unit, in which a high degree of molecular complexity can be achieved in a single step, with impressive stereochemical and regiochemical control. The Pauson-Khand Reaction investigates the nature and many variations of this reaction. Topics. | ||
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Pauson-Khand reaction. | |
| 650 | 6 | |a Réaction de Pauson-Khand. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Physical & Theoretical. |2 bisacsh | |
| 650 | 7 | |a Pauson-Khand reaction |2 fast | |
| 700 | 1 | |a Ríos Torres, Ramón. | |
| 758 | |i has work: |a The Pauson-Khand Reaction [electronic resource] (Text) |1 https://id.oclc.org/worldcat/entity/E39PD3GKB4JX4QFXJTQtMK9Kv3 |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 0 | 8 | |i Print version: |t Pauson-Khand reaction. |d Hoboken, N.J. : Wiley, 2012 |z 9780470970768 |w (DLC) 2011051669 |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=871513 |z Texto completo |
| 880 | 8 | |6 505-01/(S |a 7. Recent Advancement of Catalytic Pauson-Khand-type Reactions -- 7.1 Introduction -- 7.2 Rhodium-Catalyzed Pauson-Khand-Type Cyclizations -- 7.3 Iridium-Catalyzed Pauson-Khand-Type Cyclizations -- 7.4 Titanium-Catalyzed Pauson-Khand-Type Cyclizations -- 7.5 Ruthenium-Catalyzed Pauson-Khand-Type Cyclizations -- 7.6 Nickel- and Palladium-Catalyzed Pauson-Khand-Type Cyclizations -- 7.7 Tandem Reactions and Miscellaneous (other than Co complex) -- 7.8 Conclusion -- Acknowledgements -- References -- 8. Recent Adventures with the Pauson-Khand Reaction in Total Synthesis -- 8.1 Introduction -- 8.2 (+)-Epoxydictymene -- 8.3 (±)-Pentalenene and ( -- )-Pentalenene -- 8.4 The Tandem Pauson-Khand Reaction Directed Towards the Synthesis of Dicyclopentapentalenes -- 8.5 Enantioselective Total Synthesis of ( -- )-α-Kainic Acid -- 8.6 The Total Synthesis of Paecilomycine A -- 8.7 The Total Synthesis of (+)-Achalensolide -- 8.8 The Total Synthesis of ( -- )-Alstonerine -- 8.9 The Total Synthesis of (±)-8α-Hydroxystreptazolone -- 8.10 The Formal Total Synthesis of (±)-α- and β-Cedrene -- 8.11 Additional Applications of the Pauson-Khand Reaction in Total Synthesis -- 8.12 Conclusions -- Acknowledgements -- References -- 9. Heterogeneous Catalytic Pauson-Khand Reaction -- 9.1 Introduction -- 9.2 Development of Heterogeneous Catalysts for PKR -- 9.2.1 Polymer-Supported Catalytic Systems -- 9.2.2 Bulk Cobalt as a Catalyst -- 9.2.3 Raney Cobalt -- 9.2.4 Mesoporous Organized Zirconium Oxide Silica Powders as Catalyst -- 9.2.5 Mesoporous Graphitic Carbon as a Promoter -- 9.3 Transition Metal Nanoparticle Catalyst -- 9.3.1 Colloidal Cobalt Nanoparticles -- 9.3.2 Cobalt Nanoparticles on Charcoal -- 9.3.3 Poly(ethylene glycol)-Stabilized Cobalt Nanoparticles -- 9.4 Bimetallic Nanoparticle Catalysts -- 9.4.1 Immobilized Heterobimetallic Ru/Co Nanoparticle. | |
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