Cross sections and rate constants for physical and chemical processes /
Clasificación: | Libro Electrónico |
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Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Reston, Va. :
American Institute of Aeronautics and Astronautics,
2002.
|
Edición: | English ed. |
Colección: | Progress in astronautics and aeronautics ;
v. 196. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover
- Title
- Copyright
- Contents
- Preface
- Chapter 1 General Notions and Essential Quantities
- I. Particles and Processes Under Consideration
- II. Physical Quantities, Notations, and Units of Measurement
- A. Physical Quantities
- B. Physical Constants and Units of Measure
- III. Description and Characteristics of Interacting Particles
- A. General Notation of Particles
- B. Extended Notation of Particle States (Subscripts/Superscripts)
- C. Electronic, Vibrational, and Rotational States
- D. Statistical Weight (Multiplicity) of Electronic StatesE. Statistical Weight (Multiplicity), Vibrational Frequency, Vibrational Energy, and Characteristic Vibrational Temperature of Molecules and Molecular Ions
- F. Statistical Weight (Multiplicity), Rotational Energy, and Characteristic Rotational Temperature of Molecules and Molecular Ions
- IV. Classical Pattern of Binary Collisions of Particles
- V. Characteristic Dynamic Parameters
- A. Scales of Length and Time
- B. Characteristic Criteria
- VI. Particle Distribution over Velocities and Energy: Temperatures of Different Degrees of FreedomVII. Mean Relative Velocity of Particles in a Gas
- VIII. Partition Functions and the Mean Energy of Particles in a Gas
- A. Partition Functions
- B. Mean Energy of Particles (Per Particle)
- C. Assumptions
- IX. Heat of Reaction
- X. Relation Between Particle Number and Gas Pressure
- XI. Formulas for the Rate Constants of Specific Processes
- A. Rate Constant for Arbitrary Energy Dependence of the Process Cross Section
- B. Formulas for Cross Sections and Rate ConstantsReferences
- Chapter 2 Elastic Collisions in Gases and Plasmas (T Models)
- I. Elastic Collisions of Neutral Particles (X + Y-+X + Y)
- A. Hard-Sphere Model (T.1)
- B. Repulsive Power-Law Potential Model (T.2)
- C. Hard-Sphere Model with Variable Diameter (T.3)
- D. Model Based on Lennard�Jones Potential (T.4)
- E. Model Based on Born�Mayer Potential (T.5)
- F. Model of Attracting Particles (T.6)
- II. Elastic Collisions Involving Charged Particles
- A. Effective Radius Approximation for Electron�Atom and Electron�Molecule Collisions (T.7)B. Classical Approximation for Electron�Molecule Collisions (T.8)
- C. Born Approximation for Electron�Molecule Collisions (T.9)
- D. Model of Electron Scattering by Molecule with High Dipole Moment (T.10)
- E. Classical Approximation for Ion�Atom and Ion�Molecule Collisions (T.11)
- F. Model Based on the Born�Mayer Repulsive Potential for Ion Collisions with Neutral Particles (T.12)
- G. Model Based on the Shielded Coulomb Potential (T.13)
- References