Cyclic beta-keto esters : synthesis and reactions /
Clasificación: | Libro Electrónico |
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Autor principal: | |
Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Hauppauge, N.Y. :
Nova Science Publishers,
©2010.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- CYCLIC -KETO ESTERS: SYNTHESIS AND REACTIONS; CONTENTS; PREFACE; SYNTHESIS; 1. CARBOXYLATION OF KETONES; 2. INTRAMOLECULAR CONDENSATION AND CYCLIZATION OF SIX-MEMBERED RINGS; 3. ISOMERIZATION; 4. DIECKMANN CONDENSATION (INTRAMOLECULAR CLAISEN CONDENSATION; 5. MILLER AND NORD REACTION; 6. ESTERS OF, -DIETHYLACETONEDICARBOXYLICACID REACT WITH FORMALDEHYDE ANDMETHYLAMINE TO GIVE PYRIDONES [12]; 7. CYCLIC -KETO ESTERS OF THE TYPE (G) CAN BE PREPARED FROM CYCLIC KETONES ANDETHYL CYANOACETATE; 8. CLAISEN ACYLATION AND CARBOETHOXYLATION OF KETONES AND ESTERS [14,15].
- 9. HOMOLOGATION OF KETONES WITHETHYL DIAZOACETATE10. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE; 11. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE; 12. THE ENAMINE ACYLATION AND ALKYLATION OF CARBONYL COMPOUND; 13. SYNTHESIS OF 2-CARBOETHOXYCYCLOHEXANONE; 14. SYNTHESIS OF N-CONTAINING CYCLIC -KETO ESTERS; 15. SYNTHESIS OF, -DIFLUORO- -KETO ESTERS:; REACTIONS; 1. ALKYLATION; 2. MICHAEL REACTION; 3. ACYLATION AND ARYLATION; 4. MANNICH REACTION; 5. NITROSATION; 6. THE JAPP-KLINGEMANN REACTION; 7. REACTION WITH AMINES; 8. REACTION WITH HYDRAZINES AND ACID HYDRAZIDES; 9. REACTION WITH HYDROXYLAMINE.
- 10. REACTION WITH UREA AND THIOUREA11. REACTION WITH GUANIDINES; 12. REACTIONS WITH AMINOAZOLES; 13. REFORMATSKY REACTION; 14. REACTION WITH GLYCOLS AND DITHIOLS; 15. OXIDATION; 16. REDUCTION; 17. PECHMANN REACTION; 18. REACTION WITH HALOGENS; 19. WITTIG REACTION; 20. DECARBOXYLATION; 21. SULFURATION; 22. KNOEVENAGEL REACTION; 23. RING EXPANSION; 24. SCHMIDT REACTION; 25. KETALIZATION; 26. EFFECT OF ULTRAVIOLET LIGHT; 27. HYDROXYLATION; 28. BROMINATION AND CHLORINATION; 29. TRANSESTERIFICATION; 30. ANNELATION REACTION; 31. CYCLIZATION WITH 5-AMINOPYRAZOLES.
- 32. COUPLING WITH -(N-CARBAMOYL) ALKYLCUPRATES33. TAUTOMERIZATION; 34. ALDOL AND DEHYDRATION; 35. REACTION WITH ACETYLENE; 36. BIOTRANSFORMATION; 37. REACTION WITH 1,4- DIHALOBUTENES:; 38. CYCLIZATION OF ALKENYL -KETOESTERS AND AMIDES; 39. HYDROGENATION; 40. REACTION WITH SERINE-DERIVEDCYCLIC SULFAMIDATES; 41. RITTER REACTION; 42. SULFENYLATION; 43. REACTION WITH SODIUM HYDRIDE; 44. REACTION WITH CHIRAL CYCLIC DIOLS; 45. DEHYDROGENATION; 46. REGIOSELECTIVE CONVERSION; 47. REACTION WITH FURAN DERIVATIVES; 48. CONDENSATION WITH INDOLEETHANAMINES; 49. PHOTOLYTIC CLEAVAGE.
- 50. THERMAL SELFCONDENSATION51. CONDENSATION WITH ETHYLENE OXIDE; REFERENCES; INDEX.