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Modern trends in chemical reaction dynamics. experiment and theory / Part I :
The field of chemical reaction dynamics has made tremendous progressduring the last decade or so. This is due largely to the developmentof many new, state-of-the-art experimental and theoretical techniquesduring that period. It is beneficial to present these advances, boththeoretical and experimenta...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
River Edge, N.J. ; Hong Kong :
World Scientific,
©2004.
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| Colección: | Advanced series in physical chemistry ;
v. 14. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Introduction; Preface; CONTENTS; 1. Doppler-Selected Time-of-Flight Technique: A Versatile Three-Dimensional Velocity Mapping Approach Shih-Huang Lee and Kopin Liu; 1. Introduction; 2. Doppler-Selected Time-of-Flight Technique; 2.1. Basic Concept; 2.2. Apparatus; 2.2.1. Molecular Beam Source; 2.2.2. Laser Ionization; 2.2.3. TOF Spectrometer; 2.3. Data Analysis; 2.3.1. Crossed Beam Scattering; 2.3.2. Photodissociation Process; 2.3.3. Density-to-Flux Transformation; 3. Applications; 3.1. Photodissociation Dynamics; 3.1.1. C2H2 + hv (121.6 nm) C2H + H; 3.1.2. H2S + hv (121.6nm) SH + H.
- 3.2. Crossed-Beam Reaction Dynamics3.2.1. S(1D) + H2 SH + H; 3.2.2. F(2P) + HD HF+ D; 4. Outlook; Acknowledgments; References; 2. The Effect of Reactive Resonance on Collision Observables Sheng Der Chao and Rex T. Skodje; 1. Introduction; 2. Theoretical Methods for Resonance Phenomena; 2.1. Integral Cross-Sections; 2.2. Time Delay; 2.3. Exponential Decay; 2.4. Angular Product Distributions; 2.5. Product Rovibrational Branching Ratios; 3. Three Examples of Reactive Resonance; 3.1. F + HD HF + D; 3.2. F + H2; 3.3. H + HD; 4. Conclusions; Acknowledgments; Note Added in Proof; References.
- 3. State-to-State Dynamics of Elementary Chemical Reactions Using Rydberg H-Atom Translational Spectroscopy Xueming Yang1. Introduction; 2. The H-atom Rydberg "Tagging" TOF Method; 3. Unimolecular Dissociation of H2O; 3.1. H2O on the A1B1 Surface: A Direct Dissociation; 3.2. H2O on the B1A1 Surface: Dissociation through Conical Intersections; 3.2.1. OH Product Quantum State Distributions; 3.2.2. Rovibrational Dependent Anisotropy Parameters; 3.2.3. Effect of Parent Rotational Excitation on the OH(A) Product; 3.2.4. Accurate Dissociation Energy of H2O:D00.
- 3.2.5. Population Alternations and Quantum Interference3.2.6. Extremely Rotationally Excited OH from HOD Dissociation through Conical Intersection; 3.2.7. The Single N Propensity in the HOD + hv OD + H Dissociation Process; 4. The O(1D) + H2 Reaction: From Insertion to Abstraction; 4.1. Reaction at 1.3 kcal/mol: Barrierless Insertion Reaction; 4.2. Effect of a Single Quantum Rotational Excitation; 4.3. Experimental Evidence for a Collinear Abstraction Mechanism in O(1D) + D2 OD + D; 4.4. Quantum State Specific Dynamics for the O(1D) + HD OD + H Reaction: Isotope Effect.
- 5. Quantum-State Resolved Dynamics in the H3 System: Probing Structures and Dynamics of the Quantized Transition States5.1. The H + HD Reaction at Ec = 0.498 eV and 1.200 eV; 5.2. Probing the Structures of Quantized Transition States in the H + D2 Reaction; 6. Concluding Remarks; Acknowledgments; References; 4. Multimass Ion Imaging
- A New Experimental Method and Its Application in the Photodissociation of Small Aromatic Molecules Cheng-Liang Huang, Yuan T. Lee and Chi-Kung Ni; 1. Introduction; 2. New Experimental Method: Multimass Ion Imaging; 2.1. Overview; 2.2. Mass Spectrometer.