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Modern trends in chemical reaction dynamics. experiment and theory / Part I :

The field of chemical reaction dynamics has made tremendous progressduring the last decade or so. This is due largely to the developmentof many new, state-of-the-art experimental and theoretical techniquesduring that period. It is beneficial to present these advances, boththeoretical and experimenta...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Yang, Xueming, 1964-, Liu, Kopin
Formato: Electrónico eBook
Idioma:Inglés
Publicado: River Edge, N.J. ; Hong Kong : World Scientific, ©2004.
Colección:Advanced series in physical chemistry ; v. 14.
Temas:
Acceso en línea:Texto completo

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245 0 0 |a Modern trends in chemical reaction dynamics.  |n Part I :  |b experiment and theory /  |c editors, Xueming Yang, Kopin Liu. 
260 |a River Edge, N.J. ;  |a Hong Kong :  |b World Scientific,  |c ©2004. 
300 |a 1 online resource (xii, 526 pages) :  |b illustrations. 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
347 |a data file  |2 rda 
490 1 |a Advanced series in physical chemistry ;  |v vol. 14 
504 |a Includes bibliographical references and indexes. 
588 0 |a Print version record. 
505 0 |a Introduction; Preface; CONTENTS; 1. Doppler-Selected Time-of-Flight Technique: A Versatile Three-Dimensional Velocity Mapping Approach Shih-Huang Lee and Kopin Liu; 1. Introduction; 2. Doppler-Selected Time-of-Flight Technique; 2.1. Basic Concept; 2.2. Apparatus; 2.2.1. Molecular Beam Source; 2.2.2. Laser Ionization; 2.2.3. TOF Spectrometer; 2.3. Data Analysis; 2.3.1. Crossed Beam Scattering; 2.3.2. Photodissociation Process; 2.3.3. Density-to-Flux Transformation; 3. Applications; 3.1. Photodissociation Dynamics; 3.1.1. C2H2 + hv (121.6 nm) C2H + H; 3.1.2. H2S + hv (121.6nm) SH + H. 
505 8 |a 3.2. Crossed-Beam Reaction Dynamics3.2.1. S(1D) + H2 SH + H; 3.2.2. F(2P) + HD HF+ D; 4. Outlook; Acknowledgments; References; 2. The Effect of Reactive Resonance on Collision Observables Sheng Der Chao and Rex T. Skodje; 1. Introduction; 2. Theoretical Methods for Resonance Phenomena; 2.1. Integral Cross-Sections; 2.2. Time Delay; 2.3. Exponential Decay; 2.4. Angular Product Distributions; 2.5. Product Rovibrational Branching Ratios; 3. Three Examples of Reactive Resonance; 3.1. F + HD HF + D; 3.2. F + H2; 3.3. H + HD; 4. Conclusions; Acknowledgments; Note Added in Proof; References. 
505 8 |a 3. State-to-State Dynamics of Elementary Chemical Reactions Using Rydberg H-Atom Translational Spectroscopy Xueming Yang1. Introduction; 2. The H-atom Rydberg "Tagging" TOF Method; 3. Unimolecular Dissociation of H2O; 3.1. H2O on the A1B1 Surface: A Direct Dissociation; 3.2. H2O on the B1A1 Surface: Dissociation through Conical Intersections; 3.2.1. OH Product Quantum State Distributions; 3.2.2. Rovibrational Dependent Anisotropy Parameters; 3.2.3. Effect of Parent Rotational Excitation on the OH(A) Product; 3.2.4. Accurate Dissociation Energy of H2O:D00. 
505 8 |a 3.2.5. Population Alternations and Quantum Interference3.2.6. Extremely Rotationally Excited OH from HOD Dissociation through Conical Intersection; 3.2.7. The Single N Propensity in the HOD + hv OD + H Dissociation Process; 4. The O(1D) + H2 Reaction: From Insertion to Abstraction; 4.1. Reaction at 1.3 kcal/mol: Barrierless Insertion Reaction; 4.2. Effect of a Single Quantum Rotational Excitation; 4.3. Experimental Evidence for a Collinear Abstraction Mechanism in O(1D) + D2 OD + D; 4.4. Quantum State Specific Dynamics for the O(1D) + HD OD + H Reaction: Isotope Effect. 
505 8 |a 5. Quantum-State Resolved Dynamics in the H3 System: Probing Structures and Dynamics of the Quantized Transition States5.1. The H + HD Reaction at Ec = 0.498 eV and 1.200 eV; 5.2. Probing the Structures of Quantized Transition States in the H + D2 Reaction; 6. Concluding Remarks; Acknowledgments; References; 4. Multimass Ion Imaging -- A New Experimental Method and Its Application in the Photodissociation of Small Aromatic Molecules Cheng-Liang Huang, Yuan T. Lee and Chi-Kung Ni; 1. Introduction; 2. New Experimental Method: Multimass Ion Imaging; 2.1. Overview; 2.2. Mass Spectrometer. 
520 |a The field of chemical reaction dynamics has made tremendous progressduring the last decade or so. This is due largely to the developmentof many new, state-of-the-art experimental and theoretical techniquesduring that period. It is beneficial to present these advances, boththeoretical and experimental, in a review volume (Parts I and II). Theprimary purpose of this review volume is to provide graduate studentsand experts in the field with a rather detailed picture of the currentstatus of advanced experimental and theoretical research in chemicalreaction dynamics. All chapters in these two parts. 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Chemical kinetics. 
650 0 |a Reactivity (Chemistry) 
650 6 |a Cinétique chimique. 
650 6 |a Réactivité (Chimie) 
650 7 |a Chemical kinetics  |2 fast 
650 7 |a Reactivity (Chemistry)  |2 fast 
700 1 |a Yang, Xueming,  |d 1964-  |1 https://id.oclc.org/worldcat/entity/E39PCjrx3wKdMCxPPRythVkyMP 
700 1 |a Liu, Kopin. 
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830 0 |a Advanced series in physical chemistry ;  |v v. 14. 
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