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Atom Resolved Surface Reactions ; Nanocatalysis /
This book offers a unique perspective of the impact of scanning probe microscopies on our understanding of the surface chemistry at the nanoscale.
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | , , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Cambridge :
Royal Society of Chemistry,
2007.
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| Colección: | RSC nanoscience & nanotechnology.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Chapter 1: Some Milestones in the Development of Surface Chemistry and Catalysis-- 1 Introduction-- 2 1926: Catalysis, Theory and Practice-- Rideal and Taylor-- 3 1932: Adsorption of Gases by Solids-- Faraday Discussion, Oxford-- 4 1940: Seventeenth Faraday Lecture-- Langmuir-- 5 1950: Heterogeneous Catalysis-- Faraday Discussion, Liverpool-- 6 1957: Advances in Catalysis-- International Congress on Catalysis, Philadelphia-- 7 1963: Conference on Clean Surfaces with Supplement: Surface Phenomena in Semiconductors, New York-- 8 1966: Faraday Discussion Meeting, Liverpool-- 9 1967: The Emergence of Photoelectron Spectroscopy-- 10 1968: Berkeley Meeting: Structure and Chemistry of Solid Surfaces-- 11 1972: A Discussion on the Physics and Chemistry of Surfaces, London-- 12 1987: Faraday Symposium, Bath Summary-- References-- Further Reading-- Chapter 2: Experimental Methods in Surface Science Relevant to STM-- 1 Introduction-- 2 Kinetic Methods-- 3 Vibrational Spectroscopy-- 4 Work Function-- 5 Structural Studies-- 6 Photoelectron Spectroscopy-- 7 The Dynamics of Adsorption-- Summary-- References-- Further Reading-- Chapter 3: Scanning Tunnelling Microscopy: Theory and Experiment-- 1 The Development of Ultramicroscopy-- 2 The Theory of STM-- 3 The Interpretation of STM Images-- 4 Scanning Tunnelling Spectroscopy-- 5 The STM Experiment-- 6 The Scanner-- Sample Approach-- Adaptations of the Scanner for Specific Experiments-- 7 Making STM Tips-- Tip Materials-- References-- Chapter 4: Dynamics of Surface Reactions and Oxygen Chemisorption-- 1 Introduction-- 2 Surface Reconstruction and "Oxide" Formation-- 3 Oxygen States at Metal Surfaces-- 4 Control of Oxygen States by Coadsorbates-- 5 Adsorbate Interactions, Mobility and Residence Times-- 6 Atom-tracking STM-- 7 Hot Oxygen Adatoms: How Are They Formed?-- Summary-- References-- Further Reading-- Chapter 5: Catalytic Oxidation at Metal Surfaces: Atom Resolved Evidence-- 1 Introduction-- 2 Ammonia Oxidation-- Cu(110) Pre-exposed to Oxygen-- Coadsorption of Ammonia-Oxygen Mixtures at Cu(110)-- Coadsorption of Ammonia-Oxygen Mixtures at Mg(0001)-- Ni(110) Pre-exposed to Oxygen-- Ag(110) Pre-exposed to Oxygen-- 3 Oxidation of Carbon Monoxide-- 4 Oxidation of Hydrogen-- 5 Oxidation of Hydrocarbons-- 6 Oxidation of Hydrogen Sulfide and Sulfur Dioxide-- 7 Theoretical Analysis of Activation by Oxygen-- Summary-- References-- Further Reading-- Chapter 6: Surface Modification by Alkali Metals-- 1 Introduction-- 2 Infrared Studies of CO at Cu(110)-Cs-- 3 Structural Studies of the Alkali Metal-modified Cu(110) Surfaces-- Low-energy Electron Diffraction-- Scanning Tunnelling Microscopy-- Cu(110)-Cs System-- Oxygen Chemisorption at Cu(110)-Cs-- 4 Reactivity of Cu(110)-Cs to NH3 and CO2-- 5 Au(110)-K System-- 6 Cu(100)-Li System-- Summary-- References-- Further Reading-- Chapter 7: STM at High Pressure-- 1 Introduction-- 2 Catalysis and Chemisorption at Metals at High Pressure-- Carbon Monoxide and Nitric Oxide-- Hydrogenation of Olefins-- 3 Restructuring of the Pt(110)-(1 A-- 2) Surface by Carbon Monoxide-- 4 Adsorption-induced Step Formation-- 5 Gold Particles at FeO(111)-- 6 Hydrogen-Deuterium Exchange and Surface Poisoning-- Summary-- References-- Further Reading-- Chapter 8: Molecular and Dissociated States of Molecules: Biphasic Systems-- 1 Introduction-- 2 Nitric Oxide-- 3 Nitrogen Adatoms: Surface Structure-- 4 Carbon Monoxide-- 5 Hydrogen-- 6 Dissociative Chemisorption of HCl at Cu(110)-- 7 Chlorobenzene-- 8 Hydrocarbon Dissociation: Carbide Formation-- 9 Dissociative Chemisorption of Phenyl Iodide-- 10 Chemisorption and Trimerization of Acetylene at Pt(111)-- Summary-- References-- Further Reading-- Chapter 9: Nanoparticles and Chemical Reactivity-- 1 Introduction-- 2 Controlling Cluster Size on Surfaces-- 3 Alloy Ensembles-- 4 Nanoclusters at Oxide Surfaces-- 5 Oxidation and Polymerisation at Pd Atoms Deposited on MgO Surfaces-- 6 Clusters in Nanocatalysis-- 7 Molybdenum Sulfide Nanoclusters and Catalytic Hydrodesulfurisation Reaction Pathways-- 8 Nanoparticle Geometry at Oxide-supported Catalysts-- Summary-- References-- Further Reading-- Chapter 10: Studies of Sulfur and Thiols at Metal Surfaces-- 1 Introduction-- 2 Studies of Atomic Sulfur Adsorbed at Metal Surfaces-- Copper-- Nickel-- Gold and Silver-- Platinum, Rhodium, Ruthenium and Rhenium-- Alloy systems-- 3 Sulfur-containing Molecules-- Summary-- References-- Further Reading-- Chapter 11: Surface Engineering at the Nanoscale-- 1 Introduction-- 2 "Bottom-up" Surface Engineering-- Van der Waals Forces-- Hydrogen Bonding-- Chiral Surfaces from Prochiral Adsorbates-- Covalently Bonded Systems-- 3 Surface Engineering Using Diblock Copolymer Templates-- Summary-- References-- Further Reading-- Epilogue-- Catalysis and the Greenhouse Phenomenon-- Subject Index--