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Properties of Polymers : Their Correlation with Chemical Structure ; their Numerical Estimation and Prediction from Additive Group Contributions.

The authoritative source for polymer properties.

Detalles Bibliográficos
Clasificación:	Libro Electrónico
Autor principal:	Van Krevelen, D. W.
Otros Autores:	Te Nijenhuis, Klaas
Formato:	Electrónico eBook
Idioma:	Inglés
Publicado:	Burlington : Elsevier, 2009.
Edición:	4th ed.
Temas:	Polymers > Mechanical properties. Polymères > Propriétés mécaniques. Polymers > Mechanical properties
Acceso en línea:	Texto completo

Tabla de Contenidos:

Front Cover
Properties of Polymers Their Correlation with Chemical Structure
Their Numerical Estimation and Prediction from Additive Group Contributions
Copyright Page
Dedication Page
From the Preface to the First Edition (1972)
From the Preface to the Second Edition (1976)
Preface to the Third Edition (1990)
Introduction of the Present Author
Preface to the Fourth Edition
Acknowledgements
Contents
Part I: General Introduction: A Bird's-Eye View of Polymer Science and Engineering
Chapter 1: Polymer Properties
1.1. Approach and Objective
Bibliography
Chapter 2: Typology of Polymers
2.1. Introduction
2.2. Polymer Structure
2.3. Molar Mass and Molar Mass Distribution
2.4. Phase Transitions in Polymers
2.5. Morphology of Solid Polymers
2.6. Polymeric Liquid Crystals
2.7. Multiple Component Polymer Systems
2.8. Relaxation Phenomena
Appendix I
Appendix II
Bibliography
Chapter 3: Typology of Properties
3.1. The Concept "Polymer Properties"
3.2. Physical Quantities and Their Units
3.3. Categories of Physical Quantities
3.4. Dimensionless Groups of Quantities
3.5. Types of Molar Properties
3.6. Additive Molar Functions
Bibliography
Part II: Thermophysical Properties of Polymers
Chapter 4: Volumetric Properties
4.1. Introduction: Mass and Packing of Matter
4.2. Fundamental Quantities of Mass and Volume
4.3. Standard Molar Volumes at Room Temperature (298K)
4.4. Thermal Expansion
4.5. Isothermal Compression: Equations of State
Bibliography
Chapter 5: Calorimetric Properties
5.1. Heat Capacity
5.2. Latent Heat of Crystallization and Fusion (Melting)
5.3. Enthalpy and Entropy
Bibliography
Chapter 6: Transition Temperatures
6.1. Introduction
6.2. The Glass Transition Temperature.
6.3. The Crystalline Melting Point
6.4. Relationship Between Glass Transition Temperature and Melting Point of Polymers
6.5. Relationship Between TG, TM and Other Transition Temperatures
6.6. Transitions in Thermotropic Liquid Crystal Polymers
Appendix I
Appendix II
Bibliography
Chapter 7: Cohesive Properties and Solubility
7.1. Introduction
7.2. Cohesive Energy
7.3. Solubility
7.4. Internal Pressure
Bibliography
Chapter 8: Interfacial Energy Properties
8.1. Introduction
8.2. Surface Energy of Liquids and Melts
8.3. Surface Energy of Solid Polymers
8.4. General Expression for the Interfacial Tension
8.5. Polymer Adhesion
Bibliography
Chapter 9: Limiting Viscosity Number (Intrinsic Viscosity) and Related Properties of Very Dilute Solutions
9.1. Introduction
9.2. Molecular Dimensions of the Conformational State
9.3. The Limiting Viscosity Number (Intrinsic Viscosity)
9.4. Interrelationships of "Limiting" Diffusive Transport Quantities
Bibliography
Part III: Properties of Polymers in Fields of Force
Chapter 10: Optical Properties
10.1. Optical Properties in General
10.2. Light Refraction
10.3. Reflection and Transmission
10.4. Birefringence (and Optical Rotation)
10.5. Light Scattering
10.6. Absorption
10.7. Optical Appearance Properties
Bibliography
Chapter 11: Electrical Properties
11.1. Introduction
11.2. Dielectric Polarisation
11.3. Static Electrification and Conductivity
11.4. Ultimate Electrical Properties
Bibliography
Chapter 12: Magnetic Properties
12.1. Magnetic Susceptibility (Magnetic Inductive Capacity)
12.2. Magnetic Resonance
Bibliography
Chapter 13: Mechanical Properties of Solid Polymers
13.1. Introduction
13.2. Elastic Parameters
13.3. Rubber Elasticity
13.4. Viscoelasticity.
13.5. Ultimate Mechanical Properties
13.6. Mechanical Properties of Uniaxially Oriented Polymers (Fibres)
Bibliography
Chapter 14: Acoustic Properties
14.1. Introduction
14.2. Sound Propagation and Absorption
14.3. Additive Molar Functions for Sound Propagation
14.4. Sonic Absorption
Bibliography
Part IV: Transport Properties of Polymers
Chapter 15: Rheological Properties of Polymer Melts
15.1. Introduction
15.2. Modes of Deformation and Definition of Viscosity and Normal Stress Coefficients
15.3. Newtonian Shear Viscosity of Polymer Melts
15.4. Non-Newtonian Shear Viscosity and First Normal Stress Coefficient of Polymer Melts
15.5. Extensional Viscosity of Polymer Melts
15.6. Elastic Effects in Polymer Melts
15.7. Rheological Properties of Thermotropic Liquid Crystalline Polymers
Appendix I
Appendix II
Bibliography
Chapter 16: Rheological Properties of Polymer Solutions
16.1. Introduction
16.2. Dilute Polymer Solutions
16.3. Concentrated Polymer Solutions
16.4. Viscoelastic Properties of Polymer Solutions in Simple Shear Flow
16.5. Extensional Flow of Polymer Solutions
16.6. Solutions of Lyotropic Liquid Crystalline Polymers
Bibliography
Chapter 17: Transport of Thermal Energy
17.1. Thermal Conductivity
17.2. Appendix
Bibliography
Chapter 18: Properties Determining Mass Transfer In Polymeric Systems
18.1. Introduction
18.2. Permeation of Simple Gases
18.3. Permeations of a More Complex Nature
18.4. Dissolution of Polymers as a Case of Permeation
Bibliography
Chapter 19: Crystallisation and Recrystallisation
19.1. Crystallinity, Nucleation and Growth
19.2. Spherulitic Crystallisation of Polymers from the Melt
19.3. Induced Crystallisation of Flexible Polymeric Molecules by Pressure and Stress.
19.4. Crystallisation Phenomena in Uniaxial Drawing: Fibre Spinning
Bibliography
Part V: Properties Determining the Chemical Stability and Breakdown
Chapter 20: Thermochemical Properties
20.1. Thermodynamics and Kinetics
20.2. Calculation of the Free Enthalpy of Reaction From Group Contributions
20.3. Thermodynamics of Free Radicals
Bibliography
Chapter 21: Thermal Decomposition
21.1. Introduction
21.2. Thermal Degradation
21.3. Char Formation
21.4. Kinetics of Thermal Degradation
Bibliography
Chapter 22: Chemical Degradation
22.1. Introduction
22.2. Degradation Under the Influence of Light
22.3. Oxidative Degradation
22.4. Photo-Oxidation
22.5. Thermal Oxidation
22.6. Effects of Oxidation Degradation
22.7. Stabilisation
22.8. Hydrolytic Degradation
22.9. Stress Relaxation as a Measure of Chemical Degradation
Bibliography
Part VI: Polymer Properties as an Integral Concept
Chapter 23: Intrinsic Properties in Retrospect
23.1. Introduction
23.2. Reference Values of Intrinsic Properties Expressed as a Function of Additive Ouantities
23.3. Effect of Structural Groups on Properties
23.4. Dependence of Intrinsic Properties on Process Variables
23.5. Outlook
Chapter 24: Processing Properties
24.1. Classification of Processes
24.2. Some Important Processing Properties
24.3. Implementation of Processing Research
Bibliography
Chapter 25: Product Properties (I): Mechanical Behaviour and Failure
25.1. Introduction
25.2. Failure Mechanisms in Polymers
25.3. Deformation Properties
25.4. Toughness and Endurance
25.5. Hardness
25.6. Friction and Wear
25.7. The Mechanical Shortcomings of Homogeneous Materials and the Need for Composites
Bibliography
Chapter 26: Product Properties (II): Environmental Behaviour and Failure.
26.1. Introduction
26.2. Thermal End use Properties
26.3. Flammability and Combustion of Polymers
26.4. Environmental Decay of Polymers
Bibliography
Chapter 27: An Illustrative Example of End use Properties: Article Properties of Textile Products
27.1. Introduction
27.2. Aesthetic Properties
27.3. Use or Performance Properties
27.4. Maintenance or Care Properties
27.5. Integral Evaluation of Fibre Polymers, Fibres and Yarns By the Criteria Mentioned (Profile Method)
Bibliography
Part VII: Comprehensive Tables
I International system of units (SI)
II Survey of conversion factors
III Values of some fundamental constants
IV Physical constants of the most important solvents
V Physical properties of the most important polymers
VI Published data of ldquohigh performancerdquo polymers
VII Code symbols for the most important polymers
VIII Trade names and generic names
IX Survey of group contributions in additive molar quantities
Indexation
Symbol Index
Author index
Subject index.

Properties of Polymers : Their Correlation with Chemical Structure ; their Numerical Estimation and Prediction from Additive Group Contributions.

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