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Physical Chemistry.
Includes developments in the theories of chemical reaction kinetics and molecular quantum mechanics, as well as in the experimental study of extremely rapid chemical reactions. It proceeds from fundamental principles and shows how the consequences of these principles and postulates apply to the chem...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Burlington :
Elsevier,
2000.
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| Edición: | 2nd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Physical Chemistry; Copyright Page; Contents; Preface; Periodic Table; Information Tables; Chapter 1. Systems, States, and Processes; 1.1 Scientific Inquiry; 1.2 Systems and States; 1.3 Units of Measurements. SI Units; 1.4 State Functions; 1.5 The Relationship between Macrostates and Microstates; 1.6 Processes; Problems; Chapter 2. The Equilibrium Macroscopic States of Gases and Liquids; 2.1 Mathematical Functions and the Equilibrium Macroscopic State of a Simple System; 2.2 Real Liquids and Solids; 2.3 Real Gases; 2.4 The Coexistence of Phases and the Critical Point; Problems.
- Chapter 3. Work, Heat, and Energy: The First Law of Thermodynamics3.1 Work and the State of a System; 3.2 Heat; 3.3 Internal Energy. The First Law of Thermodynamics; 3.4 Calculation of Amounts of Heat and Energy Changes; 3.5 Enthalpy-A Convenience Variable; 3.6 Calculation of Enthalpy Changes for Non-Chemical Processes; 3.7 Calculation of Enthalpy Changes for a Class of Chemical Reactions; 3.8 Energy Changes of Chemical Reactions; Problems; Chapter 4. The Second and Third Laws of Thermodynamics: Entropy; 4.1 The Second Law of Thermodynamics and the Carnot Heat Engine.
- 4.2 The Mathematical Statement of the Second Law. Entropy4.3 The Calculation of Entropy Changes; 4.4 Statistical Entropy; 4.5 The Third Law of Thermodynamics and Absolute Entropies; Problems; Chapter 5. The Thermodynamics of Real Systems; 5.1 Criteria for Spontaneous Processes and for Equilibrium. The Gibbs and Helmholtz Energies; 5.2 Fundamental Relations for Closed Simple Systems; 5.3 Gibbs Energy Calculations; 5.4 The Description of Multicomponent and Open Systems; 5.5 Additional Useful Thermodynamic Identities; 5.6 Euler's Theorem and the Gibbs-Duhem Relation; Problems.
- Chapter 6. Phase Equilibrium6.1 The Fundamental Fact of Phase Equilibrium; 6.2 The Gibbs Phase Rule; 6.3 Phase Equilibrium in a One-Component System; 6.4 The Gibbs Energy and Phase Transitions; 6.5 Surface Structure and Thermodynamics; 6.6 Surfaces in Multicomponent Systems; Problems; Chapter 7. Multicomponent Systems; 7.1 Ideal Solutions; 7.2 Henry's Law and Dilute Nonelectrolyte Solutions; 7.3 The Activity and the Description of General Systems; 7.4 Activity Coefficients in Electrolyte Solutions; 7.5 Phase Diagrams for Nonideal Mixtures; 7.6 Colligative Properties; Problems.
- Chapter 8. The Thermodynamics of Chemical Equilibrium8.1 Gibbs Energy Changes and Equilibria of Chemical Reactions. The Equilibrium Constant; 8.2 Reactions Involving Gases and Pure Substances; 8.3 Chemical Equilibrium in Solution; 8.4 Equilibria in Solutions of Strong Electrolytes; 8.5 Acid-Base Equilibrium Calculations; 8.6 Temperature Dependence of Equilibrium Constants. The Principle of Le Châtelier; 8.7 Chemical Reactions and Biological Systems; Problems; Chapter 9. The Thermodynamics of Electrical Systems; 9.1 The Chemical Potential and the Electric Potential.