Cargando…
Modeling of Chemical Kinetics and Reactor Design.
Selecting the best type of reactor for any particular chemical reaction, taking into consideration safety, hazard analysis, scale-up, and many other factors is essential to any industrial problem. An understanding of chemical reaction kinetics and the design of chemical reactors is key to the succes...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Burlington :
Elsevier,
2001.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Modeling of Chemical Kinetics and Reactor Design; Copyright Page; Contents; Preface; Introduction; Chapter 1. Reaction Mechanisms and Rate Expressions; Introduction; Typical Reaction Mechanisms; Reaction Mechanisms; Elementary and Non-Elementary Reactions; Types of Intermediate; The Arrhenius Equation and the Collision Theory; Transition State Theory; Chain Reactions; Catalytic Reactions; Guidelines to Formulating Reaction Mechanism; Testing Kinetic Models; Chain Length; References; Chapter 2. Thermodynamics of Chemical Reactions; Introduction; Chemical Equilibrium.
- Criteria for EquilibriumReaction Equilibrium; Ideal Gas Mixtures; Real Gases-Ideal Gaseous Solutions; Real Gases; Liquid State; Determining the Fugacity and the Fugacity Coefficient; Partial Molar Quantities; Effect of Temperature on the Equilibrium Constant; Heats of Reaction; Heat Capacities of Gases; Heats of Formation; References; Appendix; Chapter 3. Reaction Rate Expression; Introduction; Reaction Rate Equation; Reaction Orders; Determining the Order of Reactions; Empirical Rate Equations of the nth Order; Method of Half-Life t1/2; Parallel Reactions; Homogeneous Catalyzed Reactions.
- Autocatalytic ReactionsIrreversible Reactions in Series; First Order Reversible Reactions; Second Order Reversible Reactions; General Reversible Reactions; Simultaneous Irreversible Side Reaction; Pseudo-Order Reaction; Practical Measurements of Reaction Rates; Regression Analysis; Weighted Least Squares Analysis; Problems and Errors in Fitting Rate Models; References; Chapter 4. Industrial and Laboratory Reactors; Introduction; Batch Isothermal Perfectly Stirred Reactor; Semi-Batch Reactors; Continuous Flow Isothermal Perfectly Stirred Tank Reactor.
- Continuous Isothermal Plug Flow Tubular ReactorContinuous Multiphase Reactors; Fluidized Bed System; Fluid Catalytic Cracking (FCC) Unit; Deep Catalytic Cracking Unit; Determining Laboratory Reactors; Guidelines for Selecting Batch Processes; Guidelines for Selecting Batch Processes; References; Chapter 5. Introduction to Reactor Design Fundamentals for Ideal Systems; Introduction; A General Approach; Ideal Isothermal Reactors; Numerical Methods for Reactor Systems Design; Reversible Series Reactions; The Semibatch Reactor; Continuous Flow Stirred Tank Reactor (CFSTR).
- Multi-Stage Continuous Flow Stirred Tank ReactorEqual Size CFSTR In Series; Space Time (ST) and Space Velocity (SV); Fractional Conversion, Yield, and Selectivity in Reactors; Relationship Between Conversion, Selectivity, and Yield; Plug Flow Reactor; Heterogeneous Tubular Reactor; Design Equation for Systems of Variable Density; Design Equations for Heterogeneous Reactions; Comparison of Ideal Reactors; CFSTR and Plug Flow Systems; Dynamic Behavior of Ideal Systems; Flow Recycle Reactor; References; Chapter 6. Non-Isothermal Reactors; Introduction.