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The Effective Crystal Field Potential.
As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free i...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Burlington :
Elsevier,
2000.
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| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 049 | |a UAMI | ||
| 100 | 1 | |a Mulak, J. | |
| 245 | 1 | 4 | |a The Effective Crystal Field Potential. |
| 260 | |a Burlington : |b Elsevier, |c 2000. | ||
| 300 | |a 1 online resource (319 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 505 | 0 | |a Front Cover; The Effective Crystal Field Potential; Copyright Page; Contents; Chapter 1. Introduction; Chapter 2. Parameterization of crystal field Hamiltonian; Chapter 3. The effective crystal field potential. Chronological development of crystal field models; Chapter 4. Ionic complex or quasi-molecular cluster. Generalized product function; Chapter 5. Point charge model (PCM); Chapter 6. One-configurational model with neglecting the non-orthogonality. The charge penetration and exchange effects. | |
| 505 | 8 | |a Chapter 7. The exclusion model. One-configurational approach with regard to non-orthogonality of the wave functionsChapter 8. Covalency contribution, i.e. the charge transfer effect; Chapter 9. Schielding and antishielding effect: contributions from closed electron shells; Chapter 10. Electrostatic crystal field contributions with consistent multipolar effects. Polarization; Chapter 11. Crystal field effect in the Stevens perturbation approach; Chapter 12. Specific mechanisms of metallic states contribut. | |
| 520 | |a As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free ions. In this way, the most simplified concept of the crystal field effect or ligand field effect in the case of individual molecules can be introduced. The conventional notion of the crystal field potential is narrowed to its non-spherical part only through ignoring the dominating spherical part whi. | ||
| 588 | 0 | |a Print version record. | |
| 504 | |a Includes bibliographical references (pages 263-286) and indexes. | ||
| 546 | |a English. | ||
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Complex compounds. | |
| 650 | 0 | |a Crystal field theory. | |
| 650 | 6 | |a Composés complexes. | |
| 650 | 6 | |a Théorie du champ cristallin. | |
| 650 | 7 | |a Complex compounds |2 fast | |
| 650 | 7 | |a Crystal field theory |2 fast | |
| 700 | 1 | |a Gajek, Z. | |
| 758 | |i has work: |a The effective crystal field potential (Text) |1 https://id.oclc.org/worldcat/entity/E39PCGgXhXBwxB8XTKxPfB7tmm |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 1 | |z 9780080436081 | |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=331902 |z Texto completo |
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