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Metal mediated template synthesis of ligands /
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chem...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Singapore ; River Edge, NJ :
World Scientific Pub. Co.,
©2004.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- The template effect. 1.1. Types of template effects. 1.2. The template effect as a molecular organizer effect. 1.3. Factors affecting the product of a template reaction. 1.4. The negative template effect. 1.5. Advantages of metal template reaction
- Alkylation reactions. 2.1. Alkylation of the nitrogen atom. 2.2. Alkylation of the sulfur atom
- Schiff condensation. 3.1. Mechanistic aspects. 3.2. Open-chain ligands. 3.3. Macrocyclic ligands. 3.4. Cage ligands. 3.5 Compartmental ligands
- Mannich condensation. 4.1. Mechanistic aspects. 4.2 Acyclic ligands. 4.3. Monocyclic ligands. 4.4. Isolated dimacrocycles. 4.5. Condensed polymacrocyclic ligands
- Self condensation of nitriles. 5.1. Phthalocyanines. 5.2. Porphyrins. 5.3. Corrole
- Self-assembled systems. 6.1. Catenanes. 6.2. Rotaxanes. 6.3. Helicates. 6.4. Knots. 6.5. Macrocycles and cages. 6.6. Racks, ladder and grids.