Functionalization of Carborane via Carboryne Intermediates

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and mo...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Zhao, Da (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Singapore : Springer Nature Singapore : Imprint: Springer, 2016.
Edición:1st ed. 2016.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Chemistry, Organic.
Physical chemistry.
Catalysis.
Organic Chemistry.
Physical Chemistry.
Acceso en línea:Texto Completo

MARC

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245 1 0 |a Functionalization of Carborane via Carboryne Intermediates  |h [electronic resource] /  |c by Da Zhao. 
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264 1 |a Singapore :  |b Springer Nature Singapore :  |b Imprint: Springer,  |c 2016. 
300 |a XVII, 170 p. 126 illus., 5 illus. in color.  |b online resource. 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
505 0 |a Introduction -- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines -- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C-H Insertion Reaction -- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition -- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes -- Ene Reaction of 1,3-Dehydro-ο-Carborane -- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling -- Conclusion -- Experimental Section. 
520 |a This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis. . 
650 0 |a Chemistry, Organic. 
650 0 |a Physical chemistry. 
650 0 |a Catalysis. 
650 1 4 |a Organic Chemistry. 
650 2 4 |a Physical Chemistry. 
650 2 4 |a Catalysis. 
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776 0 8 |i Printed edition:  |z 9789811015687 
776 0 8 |i Printed edition:  |z 9789811015700 
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830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
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950 |a Chemistry and Materials Science (SpringerNature-11644) 
950 |a Chemistry and Material Science (R0) (SpringerNature-43709) 

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