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Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C-H Bond Activation
Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Autor Corporativo: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Tokyo :
Springer Japan : Imprint: Springer,
2014.
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| Edición: | 1st ed. 2014. |
| Colección: | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Temas: | |
| Acceso en línea: | Texto Completo |
MARC
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| 001 | 978-4-431-54928-4 | ||
| 003 | DE-He213 | ||
| 005 | 20220115231710.0 | ||
| 007 | cr nn 008mamaa | ||
| 008 | 140707s2014 ja | s |||| 0|eng d | ||
| 020 | |a 9784431549284 |9 978-4-431-54928-4 | ||
| 024 | 7 | |a 10.1007/978-4-431-54928-4 |2 doi | |
| 050 | 4 | |a QD410-412.5 | |
| 072 | 7 | |a PNND |2 bicssc | |
| 072 | 7 | |a SCI013040 |2 bisacsh | |
| 072 | 7 | |a PNND |2 thema | |
| 082 | 0 | 4 | |a 547.05 |2 23 |
| 100 | 1 | |a Matsumoto, Arimasa. |e author. |4 aut |4 http://id.loc.gov/vocabulary/relators/aut | |
| 245 | 1 | 0 | |a Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C-H Bond Activation |h [electronic resource] / |c by Arimasa Matsumoto. |
| 250 | |a 1st ed. 2014. | ||
| 264 | 1 | |a Tokyo : |b Springer Japan : |b Imprint: Springer, |c 2014. | |
| 300 | |a XIII, 74 p. 105 illus. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file |b PDF |2 rda | ||
| 490 | 1 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5061 | |
| 505 | 0 | |a General Introduction -- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium -- Summary and Perspectives. | |
| 520 | |a Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the first practical example of iron catalysis in the carbon-hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C-H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society. | ||
| 650 | 0 | |a Organometallic chemistry . | |
| 650 | 0 | |a Metals. | |
| 650 | 1 | 4 | |a Organometallic Chemistry. |
| 650 | 2 | 4 | |a Metals and Alloys. |
| 710 | 2 | |a SpringerLink (Online service) | |
| 773 | 0 | |t Springer Nature eBook | |
| 776 | 0 | 8 | |i Printed edition: |z 9784431549291 |
| 776 | 0 | 8 | |i Printed edition: |z 9784431549277 |
| 776 | 0 | 8 | |i Printed edition: |z 9784431562481 |
| 830 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5061 | |
| 856 | 4 | 0 | |u https://doi.uam.elogim.com/10.1007/978-4-431-54928-4 |z Texto Completo |
| 912 | |a ZDB-2-CMS | ||
| 912 | |a ZDB-2-SXC | ||
| 950 | |a Chemistry and Materials Science (SpringerNature-11644) | ||
| 950 | |a Chemistry and Material Science (R0) (SpringerNature-43709) | ||