State-to-State Dynamical Research in the F+H2 Reaction System

This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introd...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Ren, Zefeng (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2014.
Edición:1st ed. 2014.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Physical chemistry.
Atomic structure  .
Molecular structure .
Chemistry, Physical and theoretical.
Spectrum analysis.
Physical Chemistry.
Atomic and Molecular Structure and Properties.
Theoretical Chemistry.
Spectroscopy.
Acceso en línea:Texto Completo

MARC

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245 1 0 |a State-to-State Dynamical Research in the F+H2 Reaction System  |h [electronic resource] /  |c by Zefeng Ren. 
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300 |a XII, 77 p. 64 illus., 21 illus. in color.  |b online resource. 
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505 0 |a Introduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2→DF+D. 
520 |a This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. . 
650 0 |a Physical chemistry. 
650 0 |a Atomic structure  . 
650 0 |a Molecular structure . 
650 0 |a Chemistry, Physical and theoretical. 
650 0 |a Spectrum analysis. 
650 1 4 |a Physical Chemistry. 
650 2 4 |a Atomic and Molecular Structure and Properties. 
650 2 4 |a Theoretical Chemistry. 
650 2 4 |a Spectroscopy. 
710 2 |a SpringerLink (Online service) 
773 0 |t Springer Nature eBook 
776 0 8 |i Printed edition:  |z 9783642397578 
776 0 8 |i Printed edition:  |z 9783642397554 
830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
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950 |a Chemistry and Materials Science (SpringerNature-11644) 
950 |a Chemistry and Material Science (R0) (SpringerNature-43709) 

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