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MWW-Type Titanosilicate Synthesis, Structural Modification and Catalytic Applications to Green Oxidations /

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-M...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores principales: Wu, Peng (Autor), Xu, Hao (Autor), Xu, Le (Autor), Liu, Yueming (Autor), He, Mingyuan (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2013.
Edición:1st ed. 2013.
Colección:SpringerBriefs in Green Chemistry for Sustainability,
Temas:
Acceso en línea:Texto Completo

MARC

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245 1 0 |a MWW-Type Titanosilicate  |h [electronic resource] :  |b Synthesis, Structural Modification and Catalytic Applications to Green Oxidations /  |c by Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He. 
250 |a 1st ed. 2013. 
264 1 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg :  |b Imprint: Springer,  |c 2013. 
300 |a VIII, 125 p. 79 illus., 25 illus. in color.  |b online resource. 
336 |a text  |b txt  |2 rdacontent 
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505 0 |a Introduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects. 
520 |a This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta. 
650 0 |a Catalysis. 
650 0 |a Environmental chemistry. 
650 0 |a Chemistry, Technical. 
650 0 |a Physical chemistry. 
650 1 4 |a Catalysis. 
650 2 4 |a Environmental Chemistry. 
650 2 4 |a Industrial Chemistry. 
650 2 4 |a Physical Chemistry. 
700 1 |a Xu, Hao.  |e author.  |4 aut  |4 http://id.loc.gov/vocabulary/relators/aut 
700 1 |a Xu, Le.  |e author.  |4 aut  |4 http://id.loc.gov/vocabulary/relators/aut 
700 1 |a Liu, Yueming.  |e author.  |4 aut  |4 http://id.loc.gov/vocabulary/relators/aut 
700 1 |a He, Mingyuan.  |e author.  |4 aut  |4 http://id.loc.gov/vocabulary/relators/aut 
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