MWW-Type Titanosilicate Synthesis, Structural Modification and Catalytic Applications to Green Oxidations /

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-M...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores principales: Wu, Peng (Autor), Xu, Hao (Autor), Xu, Le (Autor), Liu, Yueming (Autor), He, Mingyuan (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2013.
Edición:1st ed. 2013.
Colección:SpringerBriefs in Green Chemistry for Sustainability,
Temas:
Catalysis.
Environmental chemistry.
Chemistry, Technical.
Physical chemistry.
Environmental Chemistry.
Industrial Chemistry.
Physical Chemistry.
Acceso en línea:Texto Completo
Descripción
Sumario:This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
Descripción Física:VIII, 125 p. 79 illus., 25 illus. in color. online resource.
ISBN:9783642391156
ISSN:2452-185X

Ejemplares similares