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New Discoveries on the β-Hydride Elimination

The work presented in Thomas M. Gøgsig's thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on: (i...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Gøgsig, Thomas M. (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2012.
Edición:1st ed. 2012.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Acceso en línea:Texto Completo
Tabla de Contenidos:
  • Background
  • Palladium 1,2-migration in the Heck reaction
  • Palladium 1,2-migration in the Negishi and Kumada coupling
  • Stoichiometric studies on the palladium 1,2-migration
  • Heteroaromatic tosylates in the regio-selective Heck reaction
  • Cationic intermediates in the Ni(0)-catalyzed Heck reaction
  • Carbonylative Heck reaction
  • Conclusions.