Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel

Bruce Yoder's thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned rel...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Yoder, Bruce L. (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2012.
Edición:1st ed. 2012.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Physical chemistry.
Chemistry, Physical and theoretical.
Catalysis.
Physical Chemistry.
Theoretical Chemistry.
Acceso en línea:Texto Completo

MARC

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245 1 0 |a Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel  |h [electronic resource] /  |c by Bruce L. Yoder. 
250 |a 1st ed. 2012. 
264 1 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg :  |b Imprint: Springer,  |c 2012. 
300 |a XIII, 175 p. 125 illus., 88 illus. in color.  |b online resource. 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
505 0 |a Introduction -- Experimental Setup -- State specific preparation and alignment of gas-phase reagents -- State-resolved steric effects in methane chemisorption on Ni(100) -- State-resolved steric effects in CH4(v3) dissociation on Ni(110) -- Summary and Outlook. 
520 |a Bruce Yoder's thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas. 
650 0 |a Physical chemistry. 
650 0 |a Chemistry, Physical and theoretical. 
650 0 |a Catalysis. 
650 1 4 |a Physical Chemistry. 
650 2 4 |a Theoretical Chemistry. 
650 2 4 |a Catalysis. 
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950 |a Chemistry and Materials Science (SpringerNature-11644) 
950 |a Chemistry and Material Science (R0) (SpringerNature-43709) 

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