Late Transition Metal-Carboryne Complexes Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes /

In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molec...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Qiu, Zaozao (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2012.
Edición:1st ed. 2012.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Chemistry, Organic.
Inorganic chemistry.
Medicinal chemistry.
Organic Chemistry.
Inorganic Chemistry.
Medicinal Chemistry.
Acceso en línea:Texto Completo
Tabla de Contenidos:
  • Introduction
  • Nickel-1,2-o-Carboryne Complexes
  • Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes
  • Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes
  • Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes
  • Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes
  • Conclusion
  • Experimental Section.

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