Late Transition Metal-Carboryne Complexes Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes /

In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molec...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Qiu, Zaozao (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2012.
Edición:1st ed. 2012.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Chemistry, Organic.
Inorganic chemistry.
Medicinal chemistry.
Organic Chemistry.
Inorganic Chemistry.
Medicinal Chemistry.
Acceso en línea:Texto Completo

MARC

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245 1 0 |a Late Transition Metal-Carboryne Complexes  |h [electronic resource] :  |b Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes /  |c by Zaozao Qiu. 
250 |a 1st ed. 2012. 
264 1 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg :  |b Imprint: Springer,  |c 2012. 
300 |a XVIII, 134 p.  |b online resource. 
336 |a text  |b txt  |2 rdacontent 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
505 0 |a Introduction -- Nickel-1,2-o-Carboryne Complexes -- Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes -- Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes -- Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes -- Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes -- Conclusion -- Experimental Section. 
520 |a In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.  . 
650 0 |a Chemistry, Organic. 
650 0 |a Inorganic chemistry. 
650 0 |a Medicinal chemistry. 
650 1 4 |a Organic Chemistry. 
650 2 4 |a Inorganic Chemistry. 
650 2 4 |a Medicinal Chemistry. 
710 2 |a SpringerLink (Online service) 
773 0 |t Springer Nature eBook 
776 0 8 |i Printed edition:  |z 9783642435027 
776 0 8 |i Printed edition:  |z 9783642243622 
776 0 8 |i Printed edition:  |z 9783642243608 
830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
856 4 0 |u https://doi.uam.elogim.com/10.1007/978-3-642-24361-5  |z Texto Completo 
912 |a ZDB-2-CMS 
912 |a ZDB-2-SXC 
950 |a Chemistry and Materials Science (SpringerNature-11644) 
950 |a Chemistry and Material Science (R0) (SpringerNature-43709) 

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