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Two Studies in Gas-Phase Ion Spectroscopy Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics /

In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase....

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Simpson, Matthew J. (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2012.
Edición:1st ed. 2012.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Acceso en línea:Texto Completo

MARC

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505 0 |a Introduction and background information -- The experiments.-  Vacuum-ultraviolet negative photoion spectroscopy of SF6, CF4 and SF5CF3 -- Vacuum-ultraviolet negative photoion spectroscopy of CF3Cl, CF3Br and CF3I -- Vacuum-ultraviolet negative photoion spectroscopy of SF5Cl -- Vacuum-ultraviolet negative photoion spectroscopy of small polyatomic molecules -- The reactions of CFn+ (n = 1-3) with C2H4, C2H3F, CH2CF2 and C2HF3 -- The reactions of C2F4+ with C2H4, C2H3F, CH2CF2 and C2HF3 -- Reactions of OH-, O-, CF3-, F- and O2- with C2H4, C2H3F, CH2CF2, C2HF3 and C2F4 . 
520 |a In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules.  The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals. 
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