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Orbitals in Chemistry
Molecular properties and reactions are controlled by electrons in the molecules. Electrons had been thought to be particles. Quantum mechanics showed that el- trons have properties not only as particles but also as waves. A chemical theory is required to think about the wave properties of electrons...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor Corporativo: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Berlin, Heidelberg :
Springer Berlin Heidelberg : Imprint: Springer,
2010.
|
| Edición: | 1st ed. 2010. |
| Colección: | Topics in Current Chemistry,
289 |
| Temas: | |
| Acceso en línea: | Texto Completo |
MARC
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| 024 | 7 | |a 10.1007/978-3-642-01751-3 |2 doi | |
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| 245 | 1 | 0 | |a Orbitals in Chemistry |h [electronic resource] / |c edited by Satoshi Inagaki. |
| 250 | |a 1st ed. 2010. | ||
| 264 | 1 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg : |b Imprint: Springer, |c 2010. | |
| 300 | |a XIII, 320 p. 47 illus. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file |b PDF |2 rda | ||
| 490 | 1 | |a Topics in Current Chemistry, |x 1436-5049 ; |v 289 | |
| 505 | 0 | |a Elements of a Chemical Orbital Theory -- A Mechanistic Spectrum of Chemical Reactions -- Orbital Mixing Rules -- An Orbital Phase Theory -- Orbital Phase Environments and Stereoselectivities -- ?-Facial Selectivity of Diels-Alder Reactions -- Orbital Phase Design of Diradicals -- Relaxation of Ring Strains -- Orbitals in Inorganic Chemistry: Metal Rings and Clusters, Hydronitrogens, and Heterocyles. | |
| 520 | |a Molecular properties and reactions are controlled by electrons in the molecules. Electrons had been thought to be particles. Quantum mechanics showed that el- trons have properties not only as particles but also as waves. A chemical theory is required to think about the wave properties of electrons in molecules. These prop- ties are well represented by orbitals, which contain the amplitude and phase ch- acteristics of waves. This volume is a result of our attempt to establish a theory of chemistry in terms of orbitals - A Chemical Orbital Theory. The amplitude of orbitals represents a spatial extension of orbitals. An orbital strongly interacts with others at the position and in the direction of great extension. Orbital amplitude controls the reactivities and selectivities of chemical reactions. In the first paper on frontier orbital theory by Fukui the amplitude appeared in the form of its square, i.e., the density of frontier electrons in 1952 (Scheme 1). Orbital mixing rules were developed by Libit and Hoffmann and by Inagaki and Fukui in 1974 and Hirano and Imamura in 1975 to predict magnitudes of orbital amplitudes (Scheme 2) for understanding and designing stereoselective reactions. | ||
| 650 | 0 | |a Chemistry, Physical and theoretical. | |
| 650 | 0 | |a Atomic structure . | |
| 650 | 0 | |a Molecular structure . | |
| 650 | 0 | |a Chemistry, Organic. | |
| 650 | 1 | 4 | |a Theoretical Chemistry. |
| 650 | 2 | 4 | |a Atomic and Molecular Structure and Properties. |
| 650 | 2 | 4 | |a Organic Chemistry. |
| 700 | 1 | |a Inagaki, Satoshi. |e editor. |4 edt |4 http://id.loc.gov/vocabulary/relators/edt | |
| 710 | 2 | |a SpringerLink (Online service) | |
| 773 | 0 | |t Springer Nature eBook | |
| 776 | 0 | 8 | |i Printed edition: |z 9783642017520 |
| 776 | 0 | 8 | |i Printed edition: |z 9783642261916 |
| 776 | 0 | 8 | |i Printed edition: |z 9783642017506 |
| 776 | 0 | 8 | |i Printed edition: |z 9783662602508 |
| 830 | 0 | |a Topics in Current Chemistry, |x 1436-5049 ; |v 289 | |
| 856 | 4 | 0 | |u https://doi.uam.elogim.com/10.1007/978-3-642-01751-3 |z Texto Completo |
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| 950 | |a Chemistry and Materials Science (SpringerNature-11644) | ||
| 950 | |a Chemistry and Material Science (R0) (SpringerNature-43709) | ||