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Bio-inspired Catalysts
In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. Although all three approaches have yielded industrially viable processes, the latter two are the most widely used and can be regarded as compl...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor Corporativo: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Berlin, Heidelberg :
Springer Berlin Heidelberg : Imprint: Springer,
2009.
|
| Edición: | 1st ed. 2009. |
| Colección: | Topics in Organometallic Chemistry,
25 |
| Temas: | |
| Acceso en línea: | Texto Completo |
MARC
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| 001 | 978-3-540-87757-8 | ||
| 003 | DE-He213 | ||
| 005 | 20220114111120.0 | ||
| 007 | cr nn 008mamaa | ||
| 008 | 100301s2009 gw | s |||| 0|eng d | ||
| 020 | |a 9783540877578 |9 978-3-540-87757-8 | ||
| 024 | 7 | |a 10.1007/978-3-540-87757-8 |2 doi | |
| 050 | 4 | |a QD410-412.5 | |
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| 245 | 1 | 0 | |a Bio-inspired Catalysts |h [electronic resource] / |c edited by Thomas R. Ward. |
| 250 | |a 1st ed. 2009. | ||
| 264 | 1 | |a Berlin, Heidelberg : |b Springer Berlin Heidelberg : |b Imprint: Springer, |c 2009. | |
| 300 | |a IX, 115 p. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file |b PDF |2 rda | ||
| 490 | 1 | |a Topics in Organometallic Chemistry, |x 1616-8534 ; |v 25 | |
| 505 | 0 | |a DNA in Metal Catalysis -- Artificial Metalloproteins Exploiting Vacant Space: Preparation, Structures, and Functions -- Manganese-Substituted ?-Carbonic Anhydrase as an Enantioselective Peroxidase -- Directed Evolution of Stereoselective Hybrid Catalysts -- Artificial Metalloenzymes for Enantioselective Catalysis Based on the Biotin-Avidin Technology. | |
| 520 | |a In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. Although all three approaches have yielded industrially viable processes, the latter two are the most widely used and can be regarded as complementary in many respects. Despite the progress in structural, computational and mechanistic studies, however, to date there is no universal recipe for the optimization of catalytic processes. Thus, a trial-and-error approach remains predominant in catalyst discovery and optimization. With the aim of complementing the well-established fields of homogeneous and enzymatic catalysis, organocatalysis and artificial metalloenzymes have enjoyed a recent revival. Artificial metalloenzymes, which are the focus of this book, result from comb- ing an active but unselective organometallic moiety with a macromolecular host. Kaiser and Whitesides suggested the possibility of creating artificial metallo- zymes as long ago as the late 1970s. However, there was a widespread belief that proteins and organometallic catalysts were incompatible with each other. This severely hampered research in this area at the interface between homogeneous and enzymatic catalysis. Since 2000, however, there has been a growing interest in the field of artificial metalloenzymes for enantioselective catalysis. The current state of the art and the potential for future development are p- sented in five well-balanced chapters. G. Roelfes, B. Feringa et al. summarize research relying on DNA as a macromolecular host for enantioselective catalysis. | ||
| 650 | 0 | |a Organometallic chemistry . | |
| 650 | 0 | |a Catalysis. | |
| 650 | 0 | |a Biochemistry. | |
| 650 | 0 | |a Inorganic chemistry. | |
| 650 | 0 | |a Medicinal chemistry. | |
| 650 | 1 | 4 | |a Organometallic Chemistry. |
| 650 | 2 | 4 | |a Catalysis. |
| 650 | 2 | 4 | |a Biochemistry. |
| 650 | 2 | 4 | |a Inorganic Chemistry. |
| 650 | 2 | 4 | |a Medicinal Chemistry. |
| 700 | 1 | |a Ward, Thomas R. |e editor. |4 edt |4 http://id.loc.gov/vocabulary/relators/edt | |
| 710 | 2 | |a SpringerLink (Online service) | |
| 773 | 0 | |t Springer Nature eBook | |
| 776 | 0 | 8 | |i Printed edition: |z 9783540877868 |
| 776 | 0 | 8 | |i Printed edition: |z 9783540877561 |
| 776 | 0 | 8 | |i Printed edition: |z 9783642420672 |
| 830 | 0 | |a Topics in Organometallic Chemistry, |x 1616-8534 ; |v 25 | |
| 856 | 4 | 0 | |u https://doi.uam.elogim.com/10.1007/978-3-540-87757-8 |z Texto Completo |
| 912 | |a ZDB-2-CMS | ||
| 912 | |a ZDB-2-SXC | ||
| 950 | |a Chemistry and Materials Science (SpringerNature-11644) | ||
| 950 | |a Chemistry and Material Science (R0) (SpringerNature-43709) | ||