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Milestones in Microwave Chemistry
This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decade...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor Corporativo: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Cham :
Springer International Publishing : Imprint: Springer,
2016.
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| Edición: | 1st ed. 2016. |
| Colección: | SpringerBriefs in Green Chemistry for Sustainability,
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| Temas: | |
| Acceso en línea: | Texto Completo |
MARC
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| 001 | 978-3-319-30632-2 | ||
| 003 | DE-He213 | ||
| 005 | 20220118194705.0 | ||
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| 008 | 160322s2016 sz | s |||| 0|eng d | ||
| 020 | |a 9783319306322 |9 978-3-319-30632-2 | ||
| 024 | 7 | |a 10.1007/978-3-319-30632-2 |2 doi | |
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| 245 | 1 | 0 | |a Milestones in Microwave Chemistry |h [electronic resource] / |c edited by György Keglevich. |
| 250 | |a 1st ed. 2016. | ||
| 264 | 1 | |a Cham : |b Springer International Publishing : |b Imprint: Springer, |c 2016. | |
| 300 | |a IX, 110 p. 144 illus., 4 illus. in color. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a text file |b PDF |2 rda | ||
| 490 | 1 | |a SpringerBriefs in Green Chemistry for Sustainability, |x 2452-185X | |
| 505 | 0 | |a The Spread of the Application of the Microwave Technique in Organic Synthesis -- Microwave-Assisted Sytheses in Organic Chemistry -- The Use of MW in Organophosphorus Chemistry -- Interpretation of the Effects of Microwaves. | |
| 520 | |a This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C-C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels-Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik-Fields condensation), deoxygenations and P-C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed. | ||
| 650 | 0 | |a Chemistry, Organic. | |
| 650 | 0 | |a Chemistry, Technical. | |
| 650 | 0 | |a Science-History. | |
| 650 | 1 | 4 | |a Organic Chemistry. |
| 650 | 2 | 4 | |a Industrial Chemistry. |
| 650 | 2 | 4 | |a History of Science. |
| 700 | 1 | |a Keglevich, György. |e editor. |4 edt |4 http://id.loc.gov/vocabulary/relators/edt | |
| 710 | 2 | |a SpringerLink (Online service) | |
| 773 | 0 | |t Springer Nature eBook | |
| 776 | 0 | 8 | |i Printed edition: |z 9783319306308 |
| 776 | 0 | 8 | |i Printed edition: |z 9783319306315 |
| 830 | 0 | |a SpringerBriefs in Green Chemistry for Sustainability, |x 2452-185X | |
| 856 | 4 | 0 | |u https://doi.uam.elogim.com/10.1007/978-3-319-30632-2 |z Texto Completo |
| 912 | |a ZDB-2-CMS | ||
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| 950 | |a Chemistry and Materials Science (SpringerNature-11644) | ||
| 950 | |a Chemistry and Material Science (R0) (SpringerNature-43709) | ||