Ultrafast Dynamics of Phospholipid-Water Interfaces Studied by Nonlinear Time-Resolved Vibrational Spectroscopy /

This thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Costard, René (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cham : Springer International Publishing : Imprint: Springer, 2015.
Edición:1st ed. 2015.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Biophysics.
Physical chemistry.
Biological transport.
Cell membranes.
Atomic structure  .
Molecular structure .
Spectrum analysis.
Physical Chemistry.
Membrane Trafficking.
Atomic and Molecular Structure and Properties.
Spectroscopy.
Acceso en línea:Texto Completo

MARC

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100 1 |a Costard, René.  |e author.  |4 aut  |4 http://id.loc.gov/vocabulary/relators/aut 
245 1 0 |a Ultrafast Dynamics of Phospholipid-Water Interfaces  |h [electronic resource] :  |b Studied by Nonlinear Time-Resolved Vibrational Spectroscopy /  |c by René Costard. 
250 |a 1st ed. 2015. 
264 1 |a Cham :  |b Springer International Publishing :  |b Imprint: Springer,  |c 2015. 
300 |a X, 103 p. 42 illus., 6 illus. in color.  |b online resource. 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
505 0 |a Introduction -- Vibrational Spectroscopy -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Sites -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Shells -- Conclusions -- Appendix: Experimental Pulse Parameters. 
520 |a This thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of nonlinear vibrational spectroscopy, including femtosecond two-dimensional infrared spectroscopy. He shows for the first time that the structure of interfacial water undergoes very limited fluctuations on a 300 fs time scale and that the lifetimes of hydrogen bonds with the phospholipid are typically longer than 10 ps. Such properties originate from the steric hindrance of water fluctuations at the interface and the orienting action of strong electric fields from the phospholipid head group dipoles. In an extensive series of additional experiments, the vibrational lifetimes of the different vibrations and the processes of energy dissipation are elucidated in detail. 
650 0 |a Biophysics. 
650 0 |a Physical chemistry. 
650 0 |a Biological transport. 
650 0 |a Cell membranes. 
650 0 |a Atomic structure  . 
650 0 |a Molecular structure . 
650 0 |a Spectrum analysis. 
650 1 4 |a Biophysics. 
650 2 4 |a Physical Chemistry. 
650 2 4 |a Membrane Trafficking. 
650 2 4 |a Atomic and Molecular Structure and Properties. 
650 2 4 |a Spectroscopy. 
710 2 |a SpringerLink (Online service) 
773 0 |t Springer Nature eBook 
776 0 8 |i Printed edition:  |z 9783319220659 
776 0 8 |i Printed edition:  |z 9783319220673 
776 0 8 |i Printed edition:  |z 9783319373720 
830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
856 4 0 |u https://doi.uam.elogim.com/10.1007/978-3-319-22066-6  |z Texto Completo 
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912 |a ZDB-2-SXP 
950 |a Physics and Astronomy (SpringerNature-11651) 
950 |a Physics and Astronomy (R0) (SpringerNature-43715) 

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