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Electronic Structure of Metal Phthalocyanines on Ag(100)

The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the mole...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Krull, Cornelius (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cham : Springer International Publishing : Imprint: Springer, 2014.
Edición:1st ed. 2014.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Acceso en línea:Texto Completo

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245 1 0 |a Electronic Structure of Metal Phthalocyanines on Ag(100)  |h [electronic resource] /  |c by Cornelius Krull. 
250 |a 1st ed. 2014. 
264 1 |a Cham :  |b Springer International Publishing :  |b Imprint: Springer,  |c 2014. 
300 |a XVII, 146 p. 81 illus., 54 illus. in color.  |b online resource. 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
505 0 |a Abstract -- Introduction -- Molecular electronics -- Experimental techniques -- Introduction to the Kondo effect -- Adsorption of Metal Phthalocyanines on Ag(100) -- Electronic and magnetic properties of MePc on Ag(100) -- Doping of MePc: Alkali and Fe atoms -- Conclusions and Outlook -- Appendix: CuPc on Au(111). 
520 |a The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip. 
650 0 |a Surfaces (Physics). 
650 0 |a Optical materials. 
650 0 |a Organometallic chemistry . 
650 0 |a Spectrum analysis. 
650 0 |a Atoms. 
650 0 |a Molecules. 
650 1 4 |a Surface and Interface and Thin Film. 
650 2 4 |a Optical Materials. 
650 2 4 |a Organometallic Chemistry. 
650 2 4 |a Spectroscopy. 
650 2 4 |a Atomic, Molecular and Chemical Physics. 
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950 |a Physics and Astronomy (R0) (SpringerNature-43715)