Organotrifluoroborate Preparation, Coupling and Hydrolysis

Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a me...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Lennox, Alastair J. J. (Autor)
Autor Corporativo: SpringerLink (Online service)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cham : Springer International Publishing : Imprint: Springer, 2013.
Edición:1st ed. 2013.
Colección:Springer Theses, Recognizing Outstanding Ph.D. Research,
Temas:
Chemistry, Organic.
Catalysis.
Chemistry, Technical.
Organic Chemistry.
Industrial Chemistry.
Acceso en línea:Texto Completo

MARC

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250 |a 1st ed. 2013. 
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300 |a XV, 223 p. 308 illus., 96 illus. in color.  |b online resource. 
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505 0 |a General Introduction -- Organotrifluoroborate Preparation -- Organotrifluoroborate Coupling -- Organotrifluoroborate Hydrolysis -- Conclusions and Future Work -- Experimental: General Experimental Details -- Experimental: Organotrifluoroborate Preparation -- Experimental: Organotrifluoroborate Coupling -- Experimental: Organotrifluoroborate Hydrolysis. 
520 |a Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis. 
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650 0 |a Catalysis. 
650 0 |a Chemistry, Technical. 
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650 2 4 |a Catalysis. 
650 2 4 |a Industrial Chemistry. 
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776 0 8 |i Printed edition:  |z 9783319011356 
776 0 8 |i Printed edition:  |z 9783319011332 
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830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5061 
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950 |a Chemistry and Materials Science (SpringerNature-11644) 
950 |a Chemistry and Material Science (R0) (SpringerNature-43709) 

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